Recent developments in first-row transition metal complex-catalyzed CO2 hydrogenation

被引:17
作者
Das, Chandan [1 ]
Grover, Jagrit [1 ]
Tannu [1 ,2 ]
Das, Ayon [1 ]
Maiti, Debabrata [1 ,2 ]
Dutta, Arnab [1 ,2 ]
Lahiri, Goutam Kumar [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India
[2] Indian Inst Technol, Interdisciplinary Programme Climate Studies, Mumbai 400076, Maharashtra, India
关键词
CARBON-DIOXIDE HYDROGENATION; FORMIC-ACID; HOMOGENEOUS HYDROGENATION; SEQUENTIAL HYDROGENATION; METHANOL; FORMATE; CONVERSION; TEMPERATURE; FEEDSTOCK; AIR;
D O I
10.1039/d2dt00663d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Our modern civilization is currently standing at a crossroads due to excessive emission of anthropogenic CO2 leading to adverse climate change effects. Hence, a proper CO2 management strategy, including appropriate CO2 capture, utilization, and storage (CCUS), has become a prime concern globally. On the other hand, C-1 chemicals such as methanol (CH3OH) and formic acid (HCOOH) have emerged as leading materials for a wide range of applications in various industries, including chemical, biochemical, pharmaceutical, agrochemical, and even energy sectors. Hence, there is a concerted effort to bridge the gap between CO2 management and methanol/formic acid production by employing CO2 as a C-1-synthon. CO2 hydrogenation to methanol and formic acid has emerged as one of the primary routes for directly converting CO2 to a copious amount of methanol and formate, which is typically catalyzed by transition metal complexes. In this frontier article, we have primarily discussed the abundant first-row transition metal-driven hydrogenation reaction that has exhibited a significant surge in activity over the past few years. We have also highlighted the potential future direction of the research while incorporating a comparative analysis for the competitive second and third-row transition metal-based hydrogenation.
引用
收藏
页码:8160 / 8168
页数:9
相关论文
共 57 条
[1]   Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes [J].
Alvarez, Andrea ;
Bansode, Atul ;
Urakawa, Atsushi ;
Bavykina, Anastasiya V. ;
Wezendonk, Tim A. ;
Makkee, Michiel ;
Gascon, Jorge ;
Kapteijn, Freek .
CHEMICAL REVIEWS, 2017, 117 (14) :9804-9838
[2]   Utilisation of CO2 as a chemical feedstock:: opportunities and challenges [J].
Aresta, Michele ;
Dibenedetto, Angela .
DALTON TRANSACTIONS, 2007, (28) :2975-2992
[3]   High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].
Banerjee, Rahul ;
Phan, Anh ;
Wang, Bo ;
Knobler, Carolyn ;
Furukawa, Hiroyasu ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2008, 319 (5865) :939-943
[4]  
Behrens M, 2012, SCIENCE, V336, P893, DOI [10.1126/science.1219831, 10.1126/science.12198331]
[5]   Carbon dioxide hydrogenation catalysed by well-defined Mn(I) PNP pincer hydride complexes [J].
Bertini, Federica ;
Glatz, Mathias ;
Gorgas, Nikolaus ;
Stoeger, Berthold ;
Peruzzini, Maurizio ;
Veiros, Luis F. ;
Kirchner, Karl ;
Gonsalvi, Luca .
CHEMICAL SCIENCE, 2017, 8 (07) :5024-5029
[6]   Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands [J].
Bertini, Federica ;
Gorgas, Nikolaus ;
Stoeger, Berthold ;
Peruzzini, Maurizio ;
Veiros, Luis F. ;
Kirchner, Karl ;
Gonsalvi, Luca .
ACS CATALYSIS, 2016, 6 (05) :2889-2893
[7]   Hydrogenation of CO2 at Room Temperature and Low Pressure with a Cobalt Tetraphosphine Catalyst [J].
Burgess, Samantha A. ;
Grubel, Katarzyna ;
Appel, Aaron M. ;
Wiedner, Eric S. ;
Linehan, John C. .
INORGANIC CHEMISTRY, 2017, 56 (14) :8580-8589
[8]   Hydrogenation of CO2 in Water Using a Bis(diphosphine) Ni-H Complex [J].
Burgess, Samantha A. ;
Kendall, Alexander J. ;
Tyler, David R. ;
Linehan, John C. ;
Appel, Aaron M. .
ACS CATALYSIS, 2017, 7 (04) :3089-3096
[9]   Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System [J].
Chu, Wan-Yi ;
Culakova, Zuzana ;
Wang, Bernie T. ;
Goldberg, Karen, I .
ACS CATALYSIS, 2019, 9 (10) :9317-9326
[10]   Use of carbon dioxide as feedstock for chemicals and fuels: homogeneous and heterogeneous catalysis [J].
Dibenedetto, Angela ;
Angelini, Antonella ;
Stufano, Paolo .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2014, 89 (03) :334-353