Synthesis of Benzyl Alkyl Ethers by Intermolecular Dehydration of Benzyl Alcohol with Aliphatic Alcohols under the Effect of Copper Containing Catalysts

被引:13
作者
Bayguzina, A. R. [1 ]
Gimaletdinova, L. I. [1 ]
Khusnutdinov, R. I. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Pr Oktyabrya 141, Ufa 450075, Russia
基金
俄罗斯基础研究基金会;
关键词
UNSYMMETRICAL ETHERS; PHASE; ACID; SYSTEM;
D O I
10.1134/S1070428018080055
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Synthesis of benzyl alkyl ethers was performed in high yields by intermolecular dehydration of benzyl and primary, secondary, tertiary alcohols under the effect of copper containing catalysts. The formation of benzyl alkyl ethers occurs with participation of benzyl cation.
引用
收藏
页码:1148 / 1155
页数:8
相关论文
共 19 条
[1]  
BARLUENGA J, 1983, SYNTHESIS-STUTTGART, P53
[2]   Synergetic effect of tetrabutylammonium bromide and polyethylene glycol as phase transfer catalysts in third liquid phase for benzyl-n-butyl ether synthesis [J].
Jin, G ;
Zhang, CF ;
Ido, T ;
Goto, S .
CATALYSIS LETTERS, 2004, 98 (2-3) :107-111
[3]   Effect of third-phase properties on benzyl-n-butyl ether synthesis in phase transfer catalytic system [J].
Jin, G ;
Ido, T ;
Goto, S .
CATALYSIS TODAY, 2001, 64 (3-4) :279-287
[4]   Intermolecular dehydration of alcohols by the action of copper compounds activated with carbon tetrabromide. Synthesis of ethers [J].
Khusnutdinov, R. I. ;
Bayguzina, A. R. ;
Gimaletdinova, L. I. ;
Dzhemilev, U. M. .
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (09) :1191-1196
[5]   A novel method for synthesis of benzyl alkyl ethers using vanadium-based metal complex catalysts [J].
Khusnutdinov, R. I. ;
Bayguzina, A. R. ;
Gallyamova, L. I. ;
Dzhemilev, U. M. .
PETROLEUM CHEMISTRY, 2012, 52 (04) :261-266
[6]   Synthesis of 1-adamantyl alkyl ethers by intermolecular dehydration of 1-adamantanol with alcohols catalyzed by copper compounds [J].
Khusnutdinov, Ravil I. ;
Bayguzina, Alfiya R. ;
Mukminov, Rinat R. ;
Gimaletdinova, Leisan I. ;
Dzhemilev, Usein M. .
ARKIVOC, 2014, :342-349
[7]   EFFICIENT METHOD FOR THE REDUCTIVE CLEAVAGE OF ACETALS AND KETALS WITH ZN(BH4)2/ME3SICL [J].
KOTSUKI, H ;
USHIO, Y ;
YOSHIMURA, N ;
OCHI, M .
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (12) :2594-2596
[8]   Rhenium(I)-catalyzed formation of a carbon-oxygen bond: An efficient transition metal catalytic system for etherification of benzyl alcohols [J].
Liu, Y ;
Hua, RM ;
Sun, HB ;
Qiu, XQ .
ORGANOMETALLICS, 2005, 24 (11) :2819-2821
[9]   Synthesis and Lewis acid-catalyzed nucleophilic substitution of chiral 1-alkoxyalkyl carboxylates [J].
Matsutani, H ;
Ichikawa, S ;
Yaruva, J ;
Kusumoto, T ;
Hiyama, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4541-4542
[10]   STEREOCHEMISTRY OF (+)-(S)-2-PROPANOL-1-D3 - PARTIAL ASYMMETRIC REDUCTION OF 4',1''-DIMETHYL-1,2,3,4-DIBENZCYCLOHEPTA-1,3-DIENE-6-ONE [J].
MISLOW, K ;
SCHAEFER, H ;
OBRIEN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (10) :1940-&