Heteropolynuclear Schiff-base complexes Cu-Ln-Fe (Ln = Sm & Pr) with magnetic property

被引：7
作者：
Ding, Dan-Dan [1 ]
Gao, Ting [1 ,2 ]
Sun, Ou [1 ]
Li, Guang-Ming [1 ]
Wu, Yu-Hong [3 ]
Xu, Miao-Miao [1 ]
Zou, Xiao-Yan [1 ]
Yan, Peng-Fei [1 ]
机构：
[1] Heilongjiang Univ, Sch Chem Mat Sci, Key Lab Funct Inorgan Mat Chem MOE, Harbin 150080, Peoples R China
[2] Coll Heilongjiang Prov, Key Lab Chem Engn Proc & Technol High Efficiency, Harbin 150080, Peoples R China
[3] Heilongjiang Univ, Sch Elect Engn, Harbin 150080, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 51卷
关键词：
Heteropolynuclear; Schiff-base; 3d-4f-3d '; Dimeric; Magnetic property; METAL-COMPLEXES; 3D-4F;
D O I：
10.1016/j.inoche.2014.11.001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new complexes [{CuL}Sm(H2O)(3){Fe(CN)(6)}](2)center dot 6H(2)O (1) [{CUL}(2)Pr(H2O){Fe(CN)(6)}](2)center dot 4H(2)O (2) (H2L = N,N'-ethylenebis(3-methoxysalicylideneimine)) have been prepared by reactions of acyclic compartmental Schiffbase heterodinuclear 3d-4f compound [{CuL}Ln(NO3)(3)] (Ln = Sm & Pr) with K-3[Fe(CN)(6)]. Crystal structures of both 1 and 2 reveal unique topology structures. 1 shows a dimeric heterotrinuclear [(CuL)Sm(H2O)(3){Fe(CN)(6)}](2) while 2 displays a dimeric heterotetranuclear [{CuL}(2)Pr(H2O){Fe(CN)(6)}] with distorted sandwich moieties [{CuL}(2)Pr]. Both 1 and 2 form similar 10 ladder-like structure through the intermolecular double bridges of Cu-N bonds. The measurement of variable-temperature magnetic susceptibility reveals that both complexes 1 and 2 exhibit antiferromagnetic interaction between spin carriers. (C) 2014 Published by Elsevier B.V.
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页码：21 / 25
页数：5
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