Supramolecular semifluorinated dendrons glued by weak hydrogen-bonds

被引:7
作者
Chen, Senbin [1 ]
Meister, Annette [2 ]
Binder, Wolfgang H. [1 ]
机构
[1] Martin Luther Univ Halle Wittenberg, Chair Macromol Chem, Fac Nat Sci Chem Phys & Math 2, Von Danckelmann Pl 4, D-06120 Halle, Saale, Germany
[2] Martin Luther Univ Halle Wittenberg, Ctr Struct & Dynam Prot, Bioctr, Weinbergweg 22, D-06120 Halle, Saale, Germany
关键词
BROMO CLICK CHEMISTRY; END-FUNCTIONALIZED POLYSTYRENES; RADICAL COPOLYMERIZATION; SURFACE CHARACTERIZATION; PERFLUOROOCTYL GROUPS; PHASE SEGREGATION; PRECISE SYNTHESIS; POLYMERS; POLYMERIZATIONS; METHACRYLATES;
D O I
10.1039/c7cc04683a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
H-Bonded semifluorinated dendritic polymer networks are generated by association of macromolecules, driven by the weak diaminopyridine (DAP) and thymine (THY) couple. Solvent-dependent morphologies are observed: a continuous film structure when drop-cast from tetrahydrofuran (THF) solution or uniform nanoparticles with a diameter of similar to 50 nm in toluene.
引用
收藏
页码:8699 / 8702
页数:4
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