Electrochemical investigation of the properties of Co doped ZnO nanoparticle as a corrosion inhibitive pigment for modifying corrosion resistance of the epoxy coating

被引:118
作者
Rostami, M. [1 ]
Rasouli, S. [1 ]
Ramezanzadeh, B. [2 ]
Askari, A. [3 ]
机构
[1] Inst Color Sci & Technol, Dept Nanomat & Nanocoatings, Tehran, Iran
[2] Inst Color Sci & Technol, Dept Surface Coatings & Corros, Tehran, Iran
[3] Inst Color Sci & Technol, Tehran, Iran
关键词
Mild steel; Organic coatings; EIS; SEM; IMPEDANCE SPECTROSCOPY; ZINC; STEEL; PROTECTION; ALUMINUM; BEHAVIOR; CERIUM; NANOCONTAINERS; POLYANILINE; PARTICLES;
D O I
10.1016/j.corsci.2014.07.056
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Co doped ZnO nanoparticles were synthesized by combustion method. Then, the epoxy nanocomposites were prepared using various amounts of nanoparticles. Salt spray and electrochemical impedance spectroscopy (EIS) were used in order to investigate the corrosion inhibition effects of nanoparticles on the steel substrate. The morphology and composition of the films precipitated on the steel surface were investigated by scanning electron microscope (SEM) and energy dispersive spectroscopy. Results revealed that the corrosion inhibition properties of ZnO nanoparticle were significantly enhanced after doping with Co. Moreover, Co doped ZnO nanoparticles enhanced the corrosion resistance of the epoxy coating effectively. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:387 / 399
页数:13
相关论文
共 37 条
[1]   Corrosion inhibition of zinc by calcium exchanged beidellite clay mineral: A new smart corrosion inhibitor [J].
Aghzzaf, A. Ait ;
Rhouta, B. ;
Rocca, E. ;
Khalil, A. ;
Steinmetz, J. .
CORROSION SCIENCE, 2014, 80 :46-52
[2]   Corrosion inhibition by lithium zinc phosphate pigment [J].
Alibakhshi, E. ;
Ghasemi, E. ;
Mandavian, M. .
CORROSION SCIENCE, 2013, 77 :222-229
[3]   The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl [J].
Aramaki, K .
CORROSION SCIENCE, 2001, 43 (03) :591-604
[4]   Application of the electrochemical noise to investigate the corrosion resistance of an epoxy zinc-rich coating loaded with lamellar aluminum and micaceous iron oxide particles [J].
Arman, S. Y. ;
Ramezanzadeh, B. ;
Farghadani, S. ;
Mehdipour, M. ;
Rajabi, A. .
CORROSION SCIENCE, 2013, 77 :118-127
[5]   Mechanistic approach for evaluation of the corrosion inhibition of potassium zinc phosphate pigment on the steel surface: Application of surface analysis and electrochemical techniques [J].
Askari, F. ;
Ghasemi, E. ;
Ramezanzadeh, B. ;
Mandavian, M. .
DYES AND PIGMENTS, 2014, 109 :189-199
[6]   Kinetic properties of layer-by-layer assembled cerium zinc molybdate nanocontainers during, corrosion inhibition [J].
Bhanvase, B. A. ;
Patel, M. A. ;
Sonawane, S. H. .
CORROSION SCIENCE, 2014, 88 :170-177
[7]   Electrochemical Impedance Spectroscopy as a tool for investigating underpaint corrosion [J].
Bonora, PL ;
Deflorian, F ;
Fedrizzi, L .
ELECTROCHIMICA ACTA, 1996, 41 (7-8) :1073-1082
[8]   Electronic structure and ferromagnetism of polycrystalline Zn1-xCoxO (0≤x≤0.15) [J].
Deka, S ;
Joy, PA .
SOLID STATE COMMUNICATIONS, 2005, 134 (10) :665-669
[9]   Electrochemical investigation of the inhibition effect of CeO2 nanoparticles on the corrosion of mild steel [J].
Fedel, M. ;
Ahniyaz, A. ;
Ecco, L. G. ;
Deflorian, F. .
ELECTROCHIMICA ACTA, 2014, 131 :71-78
[10]   Resistance of metallic substrates protected by an organic coating containing aluminum powder [J].
González, S ;
Cáceres, F ;
Fox, V ;
Souto, RM .
PROGRESS IN ORGANIC COATINGS, 2003, 46 (04) :317-323