VIS and VUV spectroscopy of 12C17O and deperturbation analysis of the A1II, ν=1-5 levels

被引:13
作者
Hakalla, R. [1 ]
Niu, M. L. [2 ,3 ]
Field, R. W. [4 ]
Salumbides, E. J. [2 ,3 ,5 ]
Heays, A. N. [6 ]
Stark, G. [7 ]
Lyons, J. R. [8 ]
Eidelsberg, M. [9 ]
Lemaire, J. L. [10 ,13 ]
Federman, S. R. [11 ]
Zachwieja, M. [1 ]
Szajna, W. [1 ]
Kolek, P. [1 ]
Piotrowska, I. [1 ]
Ostrowska-Kopec, M. [1 ]
Kepa, R. [1 ]
de Oliveira, N. [12 ]
Ubachs, W. [2 ,3 ]
机构
[1] Univ Rzeszow, Fac Math & Nat Sci, Dept Expt Phys, Mat Spect Lab, Ul Prof S Pigonia 1, PL-35959 Rzeszow, Poland
[2] Vrije Univ, Dept Phys & Astron, Boelelaan 1081, NL-1081 HV Amsterdam, Netherlands
[3] Vrije Univ, LaserLaB, Boelelaan 1081, NL-1081 HV Amsterdam, Netherlands
[4] MIT, Dept Chem, Cambridge, MA 02139 USA
[5] Univ San Carlos, Dept Phys, Cebu 6000, Philippines
[6] Leiden Univ, Leiden Observ, POB 9513, NL-2300 RA Leiden, Netherlands
[7] Wellesley Coll, Dept Phys, Wellesley, MA 02481 USA
[8] Arizona State Univ, Sch Earth & Space Explorat, POB 871404, Tempe, AZ 85287 USA
[9] Observ Paris, LERMA, UMR CNRS 8112, F-92195 Meudon, France
[10] Univ Paris 11, CNRS, UMR 8214, ISMO, F-1405 Orsay, France
[11] Univ Toledo, Dept Phys & Astron, Toledo, OH 43606 USA
[12] Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
[13] Observ Paris, LERMA, Paris, France
基金
美国国家科学基金会;
关键词
4TH POSITIVE SYSTEM; HIGH-RESOLUTION; CARBON-MONOXIDE; BAND SYSTEM; PERTURBATION ANALYSIS; VACUUM-ULTRAVIOLET; ENERGY-LEVELS; 1ST ANALYSIS; MOLECULAR-CONSTANTS; FINE-STRUCTURE;
D O I
10.1039/C6RA01358A
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-accuracy dispersive optical spectroscopy measurements in the visible (VIS) region have been performed on the less-abundant (CO)-C-12-O-17 isotopologue, observing high-resolution emission bands of the B-1 Sigma(+) (nu = 0) -> A(1) II (nu = 3, 4, and 5) Angstrom system. These are combined with high-resolution photoabsorption measurements of the (CO)-C-12-O-17 B-1 Sigma(+) (nu = 0) X-1 Sigma(+) (nu = 0) and C-1 Sigma(+) (nu = 0)) X-1 Sigma(+) (nu = 0) Hopfield-Birge bands recorded with the vacuum-ultraviolet (VUV) Fourier transform spectrometer, installed on the DESIRS beamline at the SOLEIL synchrotron. The frequencies of 429 observed transitions have been determined in the 15 100-18 400 cm(-1) and 86 900-92 100 cm(-1) regions with an absolute accuracy of up to 0.003 cm(-1) and 0.005 cm(-1) for the B-A, and B-X, C-X systems, respectively. These new experimental data were combined with data from the previously analysed C -> A and B -> A systems. The comprehensive data set, 982 spectral lines belonging to 12 bands, was included in a deperturbation analysis of the A(1)II, nu = 1-5 levels of (CO)-C-12-O-17, taking into account interactions with levels in the d(3) Delta(i), e(3)Sigma(-), a(,3)Sigma(+), I-1 Sigma-and D-1 Delta states. The A(1) II and perturber states were described in terms of a set of deperturbed molecular constants, spin-orbit and L-uncoupling interaction parameters, equilibrium constants, 309 term values, as well as isotopologue-independent spin-orbit and rotation-electronic perturbation parameters.
引用
收藏
页码:31588 / 31606
页数:19
相关论文
共 95 条
[1]  
[Anonymous], 1979, Molecular Spectra and Molecular Siructure: IV. Constants of Diatomic Molecules
[2]   NEW SOURCE FOR SEARCH AND STUDY OF ELECTRONIC MOLECULAR SPECTRA - COMPOSITE WALL HOLLOW-CATHODE (CWHC) [J].
BACIS, R .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1976, 9 (12) :1081-1086
[3]   Accurate level energies in the EF1Σg+, GK1Σg+, H1Σg+, B1Σu+, C1Πu, B′1Σu+, D1Πu, I1Πg, J1Δg states of H2 [J].
Bailly, D. ;
Salumbides, E. J. ;
Vervloet, M. ;
Ubachs, W. .
MOLECULAR PHYSICS, 2010, 108 (7-9) :827-846
[4]  
Baker J., 2014, NIST AT SPECTRA DATA
[5]   FILAMENTARY STRUCTURE IN THE ORION MOLECULAR CLOUD [J].
BALLY, J ;
LANGER, WD ;
STARK, AA ;
WILSON, RW .
ASTROPHYSICAL JOURNAL, 1987, 312 (02) :L45-&
[6]   A high-resolution O-18 isotope study in the vacuum ultraviolet of the A(1)Pi->X(1)Sigma(+) 4th positive system of CO [J].
Beaty, LM ;
Braun, VD ;
Huber, KP ;
LeFloch, AC .
ASTROPHYSICAL JOURNAL SUPPLEMENT SERIES, 1997, 109 (01) :269-277
[7]  
Bensch F, 2001, ASTROPHYS J, V562, pL185, DOI 10.1086/338253
[8]   THE LOWER EXCITED-STATES OF CS - A STUDY OF EXTENSIVE SPIN-ORBIT PERTURBATIONS [J].
BERGEMAN, T ;
COSSART, D .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1981, 87 (01) :119-195
[9]   Vacuum-ultraviolet spectroscopy of Xe: Hyperfine splittings, isotope shifts, and isotope-dependent ionization energies [J].
Brandi, F ;
Velchev, I ;
Hogervorst, W ;
Ubachs, W .
PHYSICAL REVIEW A, 2001, 64 (03) :6
[10]   ACCIDENTAL PREDISSOCIATION PHENOMENA IN THE E(1)PI, V=0 AND V=1 STATES OF (CO)-C-12-O-16 AND (CO)-C-13-O-16 [J].
CACCIANI, P ;
HOGERVORST, W ;
UBACHS, W .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (21) :8308-8320