Influence of breakdown voltages on arc erosion of a Ti3AlC2 cathode in an air atmosphere

被引:27
作者
Huang, Xiaochen [1 ]
Feng, Yi [1 ,2 ]
Qian, Gang [2 ]
Zhang, Jingcheng [2 ]
Zhang, Xuebin [1 ]
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Anhui, Peoples R China
[2] Hefei Univ Technol, Instrumental Anal Ctr, Hefei 230009, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Ti3AlC2; Arc discharge; High-speed camera; Raman spectroscopy; Oxidation; Crystal transformation; MAX PHASES; ELECTRON-IRRADIATION; M(N+1)AX(N) PHASES; OXIDATION BEHAVIOR; TI3SIC2; SURFACE; TI2ALC; WATER;
D O I
10.1016/j.ceramint.2017.05.018
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The influence of breakdown voltage on arc erosion of Ti3AlC2 has been investigated. After 3-10 kV arc erosion in air, the cathode surface appeared uneven with pits, cracks and ejected particles. The arc columns were recorded by a high speed camera. By increasing the breakdown voltage, the breakdown current and erosion area increase, meanwhile breakdown strength decreases. Experimental results demonstrated that after high-energy arc erosion in air, Ti3AlC2 was oxidized to TiO2 and Al2O3. Remarkably, crystal transformation from anatase to TiO2 rutile occurred for breakdown voltage higher than 3 kV, the transformation process being completed for breakdown voltage 9 and 10 kV.
引用
收藏
页码:10601 / 10605
页数:5
相关论文
共 36 条
[1]   High-temperature oxidation behavior of un-dense Ti3AlC2 material at 1000 °C in air [J].
Ai, Taotao .
CERAMICS INTERNATIONAL, 2012, 38 (03) :2537-2541
[2]   Evaluating high-temperature modulus and elastic recovery of Ti3SiC2 and Ti3AlC2 ceramics [J].
Bao, YW ;
Zhou, Y .
MATERIALS LETTERS, 2003, 57 (24-25) :4018-4022
[3]   The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates [J].
Barsoum, MW .
PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) :201-281
[4]  
Barsoum MW, 1998, J AM CERAM SOC, V81, P785, DOI 10.1111/j.1151-2916.1998.tb02413.x
[5]   Effect of nitrogen doping on anatase-rutile phase transformation of TiO2 [J].
Bu, Xianzhong ;
Zhang, Gaoke ;
Zhang, Chonghui .
APPLIED SURFACE SCIENCE, 2012, 258 (20) :7997-8001
[6]   Anatase-to-rutile transition of titania thin films prepared by MOCVD [J].
Byun, C ;
Jang, JW ;
Kim, IT ;
Hong, KS ;
Lee, BW .
MATERIALS RESEARCH BULLETIN, 1997, 32 (04) :431-440
[7]   Influence of Ti3AlC2 on microstructure and thermal mechanical properties of Al2O3-Ti3AlC2-C refractories [J].
Chen, Junfeng ;
Li, Nan ;
Yan, Wen ;
Wei, Yaowu ;
Han, Bingqiang .
CERAMICS INTERNATIONAL, 2016, 42 (12) :14126-14134
[8]   Continuous nanoparticle generation and assembly by atmospheric pressure arc discharge [J].
Cole, Jesse J. ;
Lin, En-Chiang ;
Barry, Chad R. ;
Jacobs, Heiko O. .
APPLIED PHYSICS LETTERS, 2009, 95 (11)
[9]   The Mn+1AXn phases: Materials science and thin-film processing [J].
Eklund, Per ;
Beckers, Manfred ;
Jansson, Ulf ;
Hogberg, Hans ;
Hultman, Lars .
THIN SOLID FILMS, 2010, 518 (08) :1851-1878
[10]   ELECTRODE EROSION BY PARTICLE EJECTION IN LOW-CURRENT ARCS [J].
GRAY, EW ;
PHARNEY, JR .
JOURNAL OF APPLIED PHYSICS, 1974, 45 (02) :667-671