Opportunities and Challenges in Precise Synthesis of Transition Metal Single-Atom Supported by 2D Materials as Catalysts toward Oxygen Reduction Reaction

被引：103
作者：
Niu, Wen-Jun [1 ,2 ]
He, Jin-Zhong [1 ,2 ]
Gu, Bing-Ni [3 ,4 ,5 ]
Liu, Mao-Cheng [1 ,2 ]
Chueh, Yu-Lun [3 ,4 ,5 ]
机构：
[1] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China
[3] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan
[4] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 80424, Taiwan
[5] Natl Tsing Hua Univ, Frontier Res Ctr Fundamental & Appl Sci Matters, Hsinchu 30013, Taiwan
来源：
ADVANCED FUNCTIONAL MATERIALS | 2021年 / 31卷 / 35期
基金：
中国国家自然科学基金;
关键词：
2D materials; oxygen reduction reaction; transition metal SACs; NITROGEN-DOPED GRAPHENE; ACTIVE-SITES; ORGANIC FRAMEWORKS; HYDROGEN EVOLUTION; CARBON NANOSHEETS; ENERGY-STORAGE; ELECTROCATALYTIC PERFORMANCE; 2-DIMENSIONAL MATERIALS; UNIVERSAL PRINCIPLE; CATHODE CATALYSTS;
D O I：
10.1002/adfm.202103558
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metal single-atom catalysts (SACs) are currently a hot area of research in the field of electrocatalytic oxygen reduction reaction (ORR). In this review, the recent advances in transition metal single-atom supported by 2D materials as catalysts for ORR with high performance are reported. Due to their large surface area, uniformly exposed lattice plane, and adjustable electronic state, 2D materials are ideal supporting materials for exploring ORR active sites and surface reactions. The rational design principles and synthetic strategies of transition metal SACs supported by 2D materials are systematically introduced while the identification of active sites, their possible catalytic mechanisms as well as the perspectives on the future of transition metal SACs supported by 2D materials for ORR applications are discussed. Finally, according to the current development trend of ORR catalysts, the future opportunities and challenges of transition metal SACs supported by 2D materials are summarized.
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页数：28
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