Visible-light-mediated benzylic sp3 C-H bond functionalization to C-Br or C-N bond

被引：33

作者：

Hou, Tianyuan ^{[1
]}

Lu, Ping ^{[1
]}

Li, Pixu ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, 199 RenAi Rd, Suzhou 215123, Jiangsu, Peoples R China

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 21期

关键词：

Visible light; Photoredox; C-H functionalization; C-X bond formation; C-H amination; PHOTOREDOX CATALYSIS; DIRECT ARYLATION; PHOTOCATALYSIS; ACTIVATION;

D O I：

10.1016/j.tetlet.2016.04.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-promoted functionalization of unactivated benzylic sp(3) C-H bonds was developed. Ethylbenzene derivatives were converted to the corresponding benzyl bromides or afforded benzylamine derivatives in a one-pot manner under visible light photoredox conditions. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：2273 / 2276

页数：4

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