Visible-light-mediated benzylic sp3 C-H bond functionalization to C-Br or C-N bond

被引：33
作者：
Hou, Tianyuan [1 ]
Lu, Ping [1 ]
Li, Pixu [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, 199 RenAi Rd, Suzhou 215123, Jiangsu, Peoples R China
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 21期
关键词：
Visible light; Photoredox; C-H functionalization; C-X bond formation; C-H amination; PHOTOREDOX CATALYSIS; DIRECT ARYLATION; PHOTOCATALYSIS; ACTIVATION;
D O I：
10.1016/j.tetlet.2016.04.036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible-light-promoted functionalization of unactivated benzylic sp(3) C-H bonds was developed. Ethylbenzene derivatives were converted to the corresponding benzyl bromides or afforded benzylamine derivatives in a one-pot manner under visible light photoredox conditions. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2273 / 2276
页数：4
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