Nanocomposite hydrogel based on sodium alginate, poly (acrylic acid), and tetraamminecopper (II) sulfate as an efficient dye adsorbent

In this study, a novel nanocomposite hydrogel (NCH) was prepared by in situ crosslinking and radical polymerization of acrylic acid (AA) in the presence of sodium alginate (Na-Alg), followed by loading of Cu2+ ions and reaction with ammonia. The main advantage of the synthesized NCH is the high adsorption of dye due to the large contact area. The structure of the NCH was studied by FT-IR spectroscopy, TEM, and SEM. TEM showed that the size of nanoparticles is about 5-30 nm. The adsorption of dye was studied by changing the different factors. The removal efficiency of Crystal Violet (CV) and Malachite Green (MG) was found to be more than 96% at concentration of 10 mg/L and pH = 6. The dye adsorption on the NCH is well described by Freundlich isotherm and pseudo-second-order kinetic models. The reusability experiments showed that about 95% of the initial adsorption was obtained after eight cycles.