Adsorption and photocatalytic activity of biosynthesised ZnO nanoparticles using Aloe Vera leaf extract

In this article, we demonstrates the growth of phase pure ZnO nanostructures from Aloe-Vera leaf extract and degradation of an organic dye-Malachite Green (MG)- from aqueous medium using the same as catalyst. Adsorption mechanisms were evaluated using Lagergren's pseudo-first-order, pseudo-second-order and intraparticle diffusion kinetic models. X-Ray diffraction data showed that the synthesised ZnO is crystalline with hexagonal wurtzite phase. Average crystallite size and lattice strain was estimated from Scherrer equation and Williamson-Hall analysis with the help of Rietveld refinement data. Crystallite size obtained from Scherrer method is 12.62 nm while that from Williamson-Hall analysis is 19.27 nm. Uniform growth of ZnO nano-sheets were confirmed by FE-SEM analysis. Optical characterisation was carried by UV-Visible spectroscopy and the band gap ZnO nanoparticles was found to be 3.19 eV. Zn-O stretching vibrations were recorded at 550 cm(-1) using FTIR spectrophotometer. Results showed that biosynthesised ZnO nanosheets are particularly effective for the degradation of MG dye.