MOLECULAR AND CRYSTAL STRUCTURE OF 2,4,6-TRIAZIDOPYRIMIDINE AND ITS CHLORO-SUBSTITUTED DERIVATIVE

被引：3

作者：

Korchagin, D. V. ^{[1
]}

Aldoshin, S. M. ^{[1
]}

Chernyak, A. V. ^{[1
]}

Chapyshev, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期

关键词：

azides; pyrimidines; single-crystal XRD; molecular and crystal structure; N-15; NMR; high-energy compounds; MATRIX-ISOLATION; AZIDO GROUPS;

D O I：

10.1134/S0022476617030283

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal X-ray diffraction combined with quantum-chemical calculations and N-15 NMR spectroscopy is used to investigate the molecular and crystal structures of the high-energy 2,4,6-triazidopyrimidine and 2,4,6-triazido-5-chloropyrimidine and analyze the dependence of the structural parameters of their azido groups on the position in the pyrimidine ring.

引用

页码：618 / 623

页数：6

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