MOLECULAR AND CRYSTAL STRUCTURE OF 2,4,6-TRIAZIDOPYRIMIDINE AND ITS CHLORO-SUBSTITUTED DERIVATIVE

被引：3

作者：

Korchagin, D. V. ^{[1
]}

Aldoshin, S. M. ^{[1
]}

Chernyak, A. V. ^{[1
]}

Chapyshev, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期

关键词：

azides; pyrimidines; single-crystal XRD; molecular and crystal structure; N-15; NMR; high-energy compounds; MATRIX-ISOLATION; AZIDO GROUPS;

D O I：

10.1134/S0022476617030283

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal X-ray diffraction combined with quantum-chemical calculations and N-15 NMR spectroscopy is used to investigate the molecular and crystal structures of the high-energy 2,4,6-triazidopyrimidine and 2,4,6-triazido-5-chloropyrimidine and analyze the dependence of the structural parameters of their azido groups on the position in the pyrimidine ring.

引用

页码：618 / 623

页数：6

共 50 条

[21] CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-2-METHYL-3-PHENYLCYCLOBUT-2-ENONE
KRUEGER, SM
KAPECKI, JA
BALDWIN, JE
PAUL, LC
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1969, (07): : 796 - &
[22] Crystal and molecular structure of 2,6-dibromo-3-chloro-4-fluoroaniline
R. Betz
Crystallography Reports, 2015, 60 : 1049 - 1052
[23] Crystal and Molecular Structure of 2,6-dibromo-3-chloro-4-fluoroaniline
Betz, R.
CRYSTALLOGRAPHY REPORTS, 2015, 60 (07) : 1049 - 1052
[24] CRYSTAL AND MOLECULAR-STRUCTURE OF 2-CHLORO-4-TERT-BUTYLTHIACYCLOHEXANE SULFOXIDE
ROBERT, F
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (NOV): : 3480 - 3484
[25] Crystal structure of 4-chloro-2-iodoaniline
Quinn, Taylor R.
Tanski, Joseph M.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O944 - +
[26] First accurate molecular and crystal structure of the Meisenheimer complex of 2,4,6-trinitrobenzene
Borbulevych, OY
Kovalevsky, AY
Shishkin, OV
Atroschenko, YM
Alifanova, EN
Gitis, SS
Kaminsky, AY
Tarasova, EY
MONATSHEFTE FUR CHEMIE, 1998, 129 (05): : 467 - 472
[27] First accurate molecular and crystal structure of the Meisenheimer complex of 2,4,6-trinitrobenzene
Borbulevych O.Y.
Kovalevsky A.Y.
Shishkin O.V.
Atroschenko Y.M.
Alifanova E.N.
Gitis S.S.
Kaminsky A.Y.
Tarasova E.Y.
Monatshefte für Chemie / Chemical Monthly, 1998, 129 (5) : 467 - 472
[28] Crystal structure of 5-chloro-3-(4-fluoro-phenylsulfinyl)-2,4,6-trimethyl-1-benzofuran
Choi, Hong Dae
Lee, Uk
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1078 - +
[29] CRYSTAL AND MOLECULAR STRUCTURE OF 3-CHLORO-2-DECALONE
LAPASSET, J
FALGUEIR.J
COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1969, 268 (12): : 1097 - &
[30] MOLECULAR AND CRYSTAL-STRUCTURE OF 2'-CHLORO-2'-DEOXYURIDINE
SUCK, D
SAENGER, W
HOBBS, J
BIOCHIMICA ET BIOPHYSICA ACTA, 1972, 259 (02) : 157 - &

← 1 2 3 4 5 →