New applications of indium catalysts in organic synthesis

被引：121
作者：
Frost, CG [1 ]
Hartley, JP [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
MINI-REVIEWS IN ORGANIC CHEMISTRY | 2004年 / 1卷 / 01期
关键词：
indium; Lewis acid; catalysis; Friedel-Crafts; cycloadditions;
D O I：
10.2174/1570193043489006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Indium(Ill) salts have received considerable attention as Lewis acids in recent years. Their stability to co-ordinating atoms present in organic substrates makes them excellent catalysts in substoichiometric quantities. Stability in water allows aqueous recycling and often the use of water as a reaction solvent. This review will focus on describing new developments in the application of indium catalysts in synthetic organic chemistry. Transformations that will be covered include aromatic functionalisation, cycloaddition reactions, conjugate additions and multi-component coupling reactions.
引用
收藏
页码：1 / 7
页数：7
相关论文
共 72 条
[1]   The use of enantiomerically pure N-sulfinimines in asymmetric Baylis-Hillman reactions [J].
Aggarwal, VK ;
Castro, AMM ;
Mereu, A ;
Adams, H .
TETRAHEDRON LETTERS, 2002, 43 (08) :1577-1581
[2]   Indium triflate - An efficient catalyst for hetero Diels-Alder reactions [J].
Ali, T ;
Chauhan, KK ;
Frost, CG .
TETRAHEDRON LETTERS, 1999, 40 (30) :5621-5624
[3]   Bromolysis and iodolysis of α,β-epoxycarboxylic acids in water catalyzed by indium halides [J].
Amantini, D ;
Fringuelli, F ;
Pizzo, F ;
Vaccaro, L .
JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (13) :4463-4467
[4]  
Babu BS, 2000, TETRAHEDRON LETT, V41, P1271
[5]   Convenient synthesis of pyrano[3,2-c]quinolines and indeno[2,1-c] quinolines by imino Diels-Alder reactions [J].
Babu, G ;
Perumal, PT .
TETRAHEDRON LETTERS, 1998, 39 (20) :3225-3228
[6]   Indium trichloride (InCl3)catalyzed imino Diels-Alder reactions:: An efficient synthesis of cyclopentaquinolines, azabicyclooctanones and azabicyclononanones. [J].
Babu, G ;
Perumal, PT .
TETRAHEDRON, 1998, 54 (08) :1627-1638
[7]   Indium tribromide:: a highly effective catalyst for the addition of trimethylsilyl cyanide to α-hetero-substituted ketones [J].
Bandini, M ;
Cozzi, PG ;
Melchiorre, P ;
Umani-Ronchi, A .
TETRAHEDRON LETTERS, 2001, 42 (16) :3041-3043
[8]   A practical indium tribromide catalysed addition of indoles to nitroalkenes in aqueous media [J].
Bandini, M ;
Melchiorre, P ;
Melloni, A ;
Umani-ronchi, A .
SYNTHESIS-STUTTGART, 2002, (08) :1110-1114
[9]   Sequential one-pot InBr3-catalyzed 1,4-then 1,2-nucleophilic addition to enones [J].
Bandini, M ;
Cozzi, PG ;
Giacomini, M ;
Melchiorre, P ;
Selva, S ;
Umani-Ronchi, A .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (11) :3700-3704
[10]   GASTRIC ANTI-SECRETORY, ANTI-ULCER AND CYTOPROTECTIVE PROPERTIES OF SUBSTITUTED (E)-4-PHENYL- AND HETEROARYL-4-OXO-2-BUTENOIC ACIDS [J].
BIANCHI, M ;
BUTTI, A ;
CHRISTIDIS, Y ;
PERRONNET, J ;
BARZAGHI, F ;
CESANA, R ;
NENCIONI, A .
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 1988, 23 (01) :45-52
12345678