Sorption of Tetracycline to Varying-Sized Montmorillonite Fractions

The influence of particle sizes on sorption of tetracycline by clay minerals is poorly understood. In this study, montmorillonite clay fractions with varying particle sizes were prepared by successive centrifugation, and the effects of particle sizes on sorption of tetracycline were evaluated using an equilibrium dialysis method. Sorption isotherms were nearly overlapped for size fractions ranging from 6.38 to 16.00 mm, except for the finest clay fraction (0.41 mm). The relatively low sorption by the fraction with the smallest particles could be attributed to the colloidal nature and high edge-to-surface ratio, which could lead to reduced accessibility of tetracycline to sorption sites (particularly those at the edges). The impact of solution pH and coexisting Na+ and Ca2+ ions on tetracycline sorption was found to differ between the finest fraction and other clay fractions. The results demonstrated for the first time that clay particle size greatly influenced tetracycline sorption to clay minerals and consequently might affect their transport and bioavailability in the environment.