The mechanism of interphase mass transfer reaction and precipitation process of HDEHP-TBP-Cu-CCl4/H2C2O4-H2O system

被引：0

作者：

Zhang, Dongxiang ^{[1
]}

Ren, Zhong ^{[1
]}

Su, Xiaoming ^{[1
]}

Liu, Cong ^{[1
]}

Tarasov, V. V. ^{[2
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] Mendeleev Univ Chem Technol, Moscow 125190, Russia

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2014年 / 137卷

基金：

国家高技术研究发展计划(863计划);

关键词：

Interphase dispersed zone; Copper oxalate; Mass transfer; HDEHP; TBP; CHIRAL SEPARATION; REACTION-KINETICS; OXALATE POWDERS; EXTRACTION; ENANTIOMERS; ALCOHOLS; ACID;

D O I：

10.1016/j.seppur.2014.09.026

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A mass transfer system of H2C2O4-H2O/HDEHP (bis(2-ethylhexyl) phosphate)-TBP(tributyl phosphate)-Cu-CCl4 was established, which resulted in the production of copper oxalate precipitation. In an improved Lewis mass transfer cell, the mass transfer process between inorganic phase composed of oxalic acid water solution and the organic phase composed of HDEHP-TBP-Cu-CCl4 were researched by shifting solvents, extraction agents, the ratio of HDEHP and TBP, stirring rate, extraction time, etc. Precipitation produced by mass transfer process was characterized by IR, XRD, TG, TEM and SEM. The mass transfer reaction and system factors, which influence the size and shape of the products, were analyzed. Based on the mass transfer rate, kinetics parameters of the reaction and precipitation response of oxalic acid, HDHEP and TBP in the H2O-H2C2O4/HDEHP-TBP-Cu-CCl4 system, the theory of inter-phase dispersion zone (IDZ) in liquid-liquid system were further developed and the evolution law of dynamic microemulsion was uncovered. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：116 / 126

页数：11

共 50 条

[31] The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)2(H2O)2Co(H2O)4]•4H2O
Xie, Chengzhi
Zhang, Baofeng
Wang, Xiaoqing
Wang, Ruji
Shen, Guangqiu
Shen, Dezhong
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2007, 37 (01) : 25 - 29
[32] Reaction of Cu(CN)32- with H2O2 in water under alkaline conditions: Cyanide oxidation, Cu+/Cu2+ catalysis and H2O2 decomposition
Chen, Fayuan
Zhao, Xu
Liu, Huijuan
Qu, Jiuhui
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 158 : 85 - 90
[33] HYDROTHERMAL SYNTHESIS AND CHARACTERIZATION PROPERTIES OF C7H12N2[H2PO4]2•1/2H2O
Elwej, R.
Hannachi, N.
Adil, K.
Hlel, F.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2012, 187 (10) : 1173 - 1182
[34] Properties of the silver cyclic amide Ag2(C4H4NO2)2(H2O) crystal from the periodic DFT computations
Stashans, A.
Castillo, D.
JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (04) : 621 - 628
[35] Reply to "Comments on 'Liquid-Liquid Equilibria for the Quaternary System H3PO4-NaCl-H2O-TBP at 298.15 K'"
Liu, Chengqi
Ren, Yongsheng
Wang, Ya'nan
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (08): : 2695 - 2697
[36] A Three-Dimensional Cadmium Coordination Polymer With Tartrate Ion: Preparation, Crystal Structure, Spectroscopic, and Thermal Analyses of {[Cd(μ-C4H4O6)(H2O)3]•2H2O}∞
Tabatabaee, Masoumeh
Hoseini, Reza Mohammad
Parvez, Masood
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2014, 44 (05) : 775 - 780
[37] Desulfurization of Thioamides into Amides with H2O2/ZrCl4 Reagent System
Bahrami, Kiumars
Khodaei, Mohammad Mehdi
Tirandaz, Yeganeh
SYNTHESIS-STUTTGART, 2009, (03): : 369 - 371
[38] The behaviour of the rare earth elements during gypsum (CaSO4•2H2O) precipitation
Dutrizac, J. E.
HYDROMETALLURGY, 2017, 174 : 38 - 46
[39] STRUCTURE OF NaClO4•(H2O) n (n=1-7) HYDRATES AND EQUILIBRIUM COMPOSITION OF THE NaClO4-H2O SYSTEM
Maiorov, V. D.
Kislina, I. S.
Tarakanova, E. G.
JOURNAL OF STRUCTURAL CHEMISTRY, 2023, 64 (07) : 1165 - 1175
[40] Crystal Structure and Fluorescence Property of Dimeric Complex [Mg(phen)(H2O)4•(2,7-nds)•(phen)•4H2O]2
Guan, Lei
Wang, Ying
Sheng, Hua Fei
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (09) : 1261 - 1265

← 1 2 3 4 5 →