Easily Processable Highly Ordered Langmuir-Blodgett Films of Quaterthiophene Disiloxane Dimer for Mono layer Organic Field-Effect Transistors

被引：44

作者：

Sizov, Alexey S. ^{[1
]}

Anisimov, Daniil S. ^{[2
,3
]}

Agina, Elena V. ^{[1
]}

Borshchey, Oleg V. ^{[1
]}

Bakirov, Artem V. ^{[1
]}

Shcherbina, Maxim A. ^{[1
]}

Grigorian, Souren ^{[4
]}

Bruevich, Vladimir V. ^{[2
,3
]}

Chvalun, Sergei N. ^{[1
]}

Paraschuk, Dmitry Yu. ^{[2
,3
]}

Ponomarenko, Sergei A. ^{[1
,5
]}

机构：

[1] Russian Acad Sci, Inst Synthet Polymer Mat, Moscow 117393, Russia

[2] Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Ctr Int Laser, Moscow 119991, Russia

[4] Univ Siegen, Inst Phys, D-57068 Siegen, Germany

[5] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

LANGMUIR | 2014年 / 30卷 / 50期

关键词：

SELF-ASSEMBLED MONOLAYERS; CHARGE-CARRIER MOBILITY; UNIVERSAL FORCE-FIELD; REGIOREGULAR POLY(3-HEXYLTHIOPHENE); TRANSPORT-PROPERTIES; MOLECULAR-STRUCTURE; SEMICONDUCTORS; BEHAVIOR; SIMULATIONS; PERFORMANCE;

D O I：

10.1021/la504037b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembly of highly soluble water-stable tetramethyldisiloxane-based dimer of a,a'-dialkylquaterthiophene on the waterair interface was investigated by Langmuir, grazing incidence X-ray diffraction, and X-ray reflectivity techniques. The conditions for formation of very homogeneous crystalline monolayer Langmuir-Blodgett (LB) films of the oligomer were found. Monolayer organic field-effect transistors (OFETs) based on these LB films as a semiconducting layer showed hole mobilities up to 3 x 10(-3) cm(2)/(V s), onoff ratio of 10(5), small hysteresis, and high long-term stability. The electrical performance of the LB films studied is close to that for the same material in the bulk or in the monolayer OFETs prepared from water vapor sensitive chlorosilyl derivatives of quaterthiophene by self-assembling from solution. These findings show high potential of disiloxane-based LB films in monolayer OFETs for large-area organic electronics.

引用

页码：15327 / 15334

页数：8

共 53 条

[1] Formation of Self-Assembled Organosilicon-Functionalized Quinquethiophene Monolayers by Fast Processing Techniques [J].

Agina, Elena V. ;

Usov, Ivan A. ;

Borshchev, Oleg V. ;

Wang, Jingbo ;

Mourran, Ahmed ;

Shcherbina, Maxim A. ;

Bakirov, Artem V. ;

Grigorian, Souren ;

Moeller, Martin ;

Chvalun, Sergei N. ;

Ponomarenko, Sergei A. .

LANGMUIR, 2012, 28 (46) :16186-16195

[2] Effect of Molecular Structure of α,α′-Dialkylquaterthiophenes and Their Organosilicon Multipods on Ordering, Phase Behavior, and Charge Carrier Mobility [J].

Anokhin, Denis. V. ;

Defaux, Matthieu ;

Mourran, Ahmed ;

Moeller, Martin ;

Luponosov, Yury N. ;

Borshchev, Oleg V. ;

Bakirov, Artem V. ;

Shcherbina, Maxim A. ;

Chvalun, Sergei N. ;

Meyer-Friedrichsen, Timo ;

Elschner, Andreas ;

Kirchmeyer, Stephan ;

Ponomarenko, Sergei A. ;

Ivanov, Dmitri A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (43) :22727-22736

[3] Self-Assembled Organic Semiconductors for Monolayer Field-Effect Transistors [J].

Borshchev, O. V. ;

Ponomarenko, S. A. .

POLYMER SCIENCE SERIES C, 2014, 56 (01) :32-46

[4] Gate-bias assisted charge injection in organic field-effect transistors [J].

Brondijk, J. J. ;

Torricelli, F. ;

Smits, E. C. P. ;

Blom, P. W. M. ;

de Leeuw, D. M. .

ORGANIC ELECTRONICS, 2012, 13 (09) :1526-1531

[5] High-Performance Langmuir-Blodgett Monolayer Transistors with High Responsivity [J].

Cao, Yang ;

Wei, Zhongming ;

Liu, Song ;

Gan, Lin ;

Guo, Xuefeng ;

Xu, Wei ;

Steigerwald, Michael L. ;

Liu, Zhongfan ;

Zhu, Daoben .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (36) :6319-6323

[6] APPLICATION OF A UNIVERSAL FORCE-FIELD TO ORGANIC-MOLECULES [J].

CASEWIT, CJ ;

COLWELL, KS ;

RAPPE, AK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10035-10046

[7] Unique Role of Self-Assembled Monolayers in Carbon Nanomaterial-Based Field-Effect Transistors [J].

Chen, Hongliang ;

Guo, Xuefeng .

SMALL, 2013, 9 (08) :1144-1159

[8] Solution-Processable Septithiophene Monolayer Transistor [J].

Defaux, Matthieu ;

Gholamrezaie, Fatemeh ;

Wang, Jingbo ;

Kreyes, Andreas ;

Ziener, Ulrich ;

Anokhin, Denis V. ;

Ivanov, Dimitri A. ;

Moser, Armin ;

Neuhold, Alfred ;

Salzmann, Ingo ;

Resel, Roland ;

de Leeuw, Dago M. ;

Meskers, Stefan C. J. ;

Moeller, Martin ;

Mourran, Ahmed .

ADVANCED MATERIALS, 2012, 24 (07) :973-+

[9] Spatially correlated charge transport in organic thin film transistors [J].

Dinelli, F ;

Murgia, M ;

Levy, P ;

Cavallini, M ;

Biscarini, F ;

de Leeuw, DM .

PHYSICAL REVIEW LETTERS, 2004, 92 (11) :116802-1

[10] Thin film transistors based on alkylphenyl quaterthiophenes: Structure and electrical transport properties [J].

Fritz, Sandra E. ;

Mohapatra, Siddharth ;

Holmes, Brian T. ;

Anderson, Amelia M. ;

Prendergast, Cathal F. ;

Frisbie, C. Daniel ;

Ward, Michael D. ;

Toney, Michael F. .

CHEMISTRY OF MATERIALS, 2007, 19 (06) :1355-1361

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