1,8-Anthrancene disulfonamide: A simple but highly sensitive and selective fluorescent chemosensor for Hg2+ in aqueous media

被引:11
作者
Hu, Zhi-Qiang [1 ]
Yang, Xu-Dong [1 ]
Cui, Cun-Li [1 ]
Ding, Lei [1 ]
Lin, Cun-Sheng [1 ]
Lu, Hai-Yan [2 ]
Wang, Lei [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Shandong 266042, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorescent chemosensor; 1,8-Anthrancence disulfonamide; Hg(II); Aqueous media; 1:1 complex; HG2+-SELECTIVE CHEMODOSIMETER; SENSOR MOLECULES; MERCURY LEVELS; ION; RECOGNITION; SPIROLACTAM; EXTRACTION; HG(II); WATER;
D O I
10.1016/j.snb.2009.11.020
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
New 1,8-anthrancene disulfonamide derivative 1 was designed and synthesized as a selective fluorescent sensor for Hg2+ over miscellaneous metal ions in aqueous media. Upon mixing with Hg2+ in DMSO:H2O (2:98, v/v), the decrease of fluorescence intensity and a bathochromic shift of absorbance of 1 could be observed. The Job plot indicated the formation of 1:1 complex between 1 and He. Background metal ions showed small or no interference with the detection of Hg2+. The binding mode and effect of N-substituent groups were also investigated. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:61 / 65
页数:5
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