Water vapor corrosion behavior and failure mechanism of plasma sprayed mullite/Lu2Si2O7-Lu2SiO5 coatings

被引：27

作者：

Hu, Xunxun ^{[1
]}

Xu, Fangfang ^{[2
]}

Li, Kunwei ^{[3
]}

Jin, Gen ^{[4
]}

Xu, Yue ^{[4
]}

Zhao, Xinqing ^{[1
]}

机构：

[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China

[2] Guobiao Beijing Testing & Certificat Co Ltd, 2 Xinjiekouwai St, Beijing 100088, Peoples R China

[3] China Natl Inst Standardizat, 4 Zhichun Rd, Beijing 100191, Peoples R China

[4] Beihang Univ, Sch Chem, Beijing 100191, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2018年 / 44卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Lutetium silicates; Environmental barrier coatings; Inter-diffusion; Corrosion; Failure; ENVIRONMENTAL BARRIER COATINGS; MULLITE; OXIDATION; DURABILITY; RECESSION; COMPOSITES;

D O I：

10.1016/j.ceramint.2018.05.020

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new coating with mullite as the inner layer and Lu2Si2O7-Lu2SiO5 (lutetium disilicate-lutetium monosilicate, LuDS LuMS) composite as the top layer was designed and fabricated on the surface of porous SIC substrate by atmospheric plasma spraying (APS). The microstructure evolution, phase transformation, inter-diffusion and failure mechanism of the coated samples during steam cycling at 1450 degrees C were systemically investigated. The results indicated that the coated samples maintain weight gain and the average weight gain rate is 1.12 X 10(-1) mg/cm(2) h. The thermal expansion coefficient (CTE) mismatches between the coating and the substrate as well as between the two ceramic layers have produced a thermal mismatch stress. In addition, the chemical reaction induced the sintering of LuDS-LuMS layer, the amorphous-crystalline phase transformation and the transformation between LuDS and LuMS phases could result in aging stress. With the accumulation of thermal mismatch stress and aging stress, the through and horizontal cracks have appeared in the coating, leading to the coating failure.

引用

页码：14177 / 14185

页数：9

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