Hydrothermal synthesis, crystal structure and electrochemical property of a novel 3-D microporous reduced molybdophosphate with large cavities

被引：6

作者：

Guo, Hong-Xu ^{[1
]}

Li, Xi-Zhong ^{[1
]}

Weng, Wen ^{[1
]}

机构：

[1] Zhangzhou Normal Univ, Dept Chem & Environm Sci, Zhangzhou 363000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Reduced molybdophosphate; 3-D open framework; Hydrothermal synthesis; Large cavities; Crystal structure; Electrochemical; BOND-VALENCE PARAMETERS; COORDINATION-COMPLEXES; IRON MOLYBDOPHOSPHATE; MOLYBDENUM PHOSPHATE; CLUSTER; OCTAMOLYBDATE; FRAMEWORK; TUNNELS; POLYMER; ZINC;

D O I：

10.1016/j.inoche.2010.04.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel molybdenum phosphate based on [Mo6P4] inorganic subunits and [Mn(H2O)(2)](2+) cations, Mn[Mo6O12(OH)(3)(PO4)(HPO4)(2)(H2PO4)](2)[Mn(H2O)(2)](2)(Hen)(4)center dot 13H(2)O (en = ethyl enediamine), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, EPR spectrum and TGA analysis. The 3-D framework of the compound contains microporous structure with large cavities filled by mono-protonated Hen(+) and water molecules. The electrochemical behavior of the compound has been also studied. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：909 / 913

页数：5

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