Hydrothermal synthesis, crystal structure and electrochemical property of a novel 3-D microporous reduced molybdophosphate with large cavities

被引：6

作者：

Guo, Hong-Xu ^{[1
]}

Li, Xi-Zhong ^{[1
]}

Weng, Wen ^{[1
]}

机构：

[1] Zhangzhou Normal Univ, Dept Chem & Environm Sci, Zhangzhou 363000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Reduced molybdophosphate; 3-D open framework; Hydrothermal synthesis; Large cavities; Crystal structure; Electrochemical; BOND-VALENCE PARAMETERS; COORDINATION-COMPLEXES; IRON MOLYBDOPHOSPHATE; MOLYBDENUM PHOSPHATE; CLUSTER; OCTAMOLYBDATE; FRAMEWORK; TUNNELS; POLYMER; ZINC;

D O I：

10.1016/j.inoche.2010.04.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel molybdenum phosphate based on [Mo6P4] inorganic subunits and [Mn(H2O)(2)](2+) cations, Mn[Mo6O12(OH)(3)(PO4)(HPO4)(2)(H2PO4)](2)[Mn(H2O)(2)](2)(Hen)(4)center dot 13H(2)O (en = ethyl enediamine), has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, EPR spectrum and TGA analysis. The 3-D framework of the compound contains microporous structure with large cavities filled by mono-protonated Hen(+) and water molecules. The electrochemical behavior of the compound has been also studied. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：909 / 913

页数：5

共 45 条

[1] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[3] Hydrothermal synthesis and crystal structure of [{Cu(2,2′-bpy)2}2Mo8O26]:: a β-octamolybdate cluster covalently bonded to two {Cu(2,2′-bpy)2}2+ coordination complexes via bridging oxo groups [J].

Chen, LD ;

Wang, YH ;

Hu, CW ;

Feng, LY ;

Wang, EB ;

Hu, NH ;

Jia, HQ .

JOURNAL OF SOLID STATE CHEMISTRY, 2001, 161 (01) :173-176

[4] A novel 3D network structure constructed from centrosymmetric sodium-phosphomolybdate bonding by sodium and zinc atoms [J].

Chen, Xinqin ;

Lin, Shen ;

Chen, Lijuan ;

Chen, Xiaohua ;

Liu, Chunlian ;

Chen, Jiebo ;

Yang, Liuyi .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (11) :1285-1288

[5] A new 3D cadmium molybdenum phosphate with intersecting tunnels:: hydrothermal synthesis, structure and electrochemical properties of [C3H12N2]4[CdMo12O24(HPO4)6(PO4)2(OH)6][(Cd(H2O))2].3H2O [J].

Duan, LY ;

Liu, FC ;

Wang, XL ;

Wang, EB ;

Qin, C ;

Li, YG ;

Wang, XL ;

Hu, CW .

JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) :15-20

[6] A two-dimensional zinc-molybdenum(V) phosphate organic-inorganic hybrid polymer with fluorescence [J].

Guo, Hong-Xu ;

Liu, Ka-Ming ;

Zhu, Guo-Hui .

JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (7-9) :815-823

[7] A novel 3D organic-inorganic hybrid based on sandwich-type cadmium hetereopolymolybdate:: {[Cd4(H2O)2(2,2′-bpy)2] Cd[Mo6O12(OH)3(PO4)2(HPO4)2]2} [Mo2O4(2,2′-bpy)2]2•3H2O [J].

Guo, HX ;

Liu, SX .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (11) :1217-1220

[8]

GUO HX, 2008, INORG CHEM COMMUN, V1, P382

[9]

GUO HX, 2005, J MOL STRUCT, V229, P741

[10] Two-dimensional network constructed from hexamolybdate, octamolybdate and [Cu3(4,7-phen)3]3+ clusters:: [{Cu3(4,7-phen)3}2{Mo14O45}] [J].

Hagrman, D ;

Zapf, PJ ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 1998, (12) :1283-1284

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