Gabuda's model of averaging local magnetic fields in solid-state NMR. The mobility of atoms and molecules

被引:7
|
作者
Kozlova, S. G. [1 ]
Sergeev, N. A. [2 ]
Buznik, V. M. [3 ,4 ]
机构
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Univ Szczecin, Inst Phys, PL-70453 Szczecin, Poland
[3] All Russian Sci Res Inst Aviat Mat, Moscow, Russia
[4] Tomsk Natl Res State Univ, Tomsk, Russia
关键词
NMR; mobility of atoms and molecules; solids; minerals; sorbents; hydrated proteins; WATER-MOLECULES; GUEST SUBLATTICE; STRUCTURAL TRANSFORMATIONS; SPONTANEOUS POLARIZATION; PHASE-TRANSITION; ZEOLITE WATER; SQUARIC ACID; BOUND WATER; RESONANCE; DIFFUSION;
D O I
10.1134/S0022476616020013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The review presents the main results of the studies of Prof. S. P. Gabuda, which were devoted to the NMR investigation of the mobility of atoms and molecules. The basic principles of his model for averaging local magnetic fields under the conditions of atomic and molecular mobility are outlined. This model provides a relationship between the parameters of these fields with the structural features of the mobility of atoms and molecules and intermolecular interactions. Ionic and molecular crystals, zeolites, molecular sieves, hydrated proteins, and so on are considered. Phase transitions in guest subsystems, effects of dynamic disordering and correlated electron motion on the mobility of atoms and molecules and their location are discussed.
引用
收藏
页码:213 / 237
页数:25
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