Dynamic complexation of solutes in capillary electrophoresis

被引：14
作者：
Bowser, MT [1 ]
Chen, DDY [1 ]
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
来源：
ELECTROPHORESIS | 1998年 / 19卷 / 03期
关键词：
separation theory; dynamic complexation capillary electrophoresis; capacity factor; multiple equilibria; higher order interactions;
D O I：
10.1002/elps.1150190304
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
The analyte migration behavior in any chemical separation system can be described using a single equation that unifies all areas of separation science. This equation can be used in capillary electrophoresis (CE) to design separation systems, and to study interactions between analytes and additives. By using individual capacity factors for each analyte species present in the system, and with the knowledge of the characteristics of each interaction, one can predict the analyte migration behavior in complicated CE systems, including systems with multiple 1:1 interactions and/or higher order interactions.
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页码：383 / 387
页数：5
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