A 3D Metal-organic Framework Containing [Cd(3-CPOA)]n (3-CPOA2-=3-Carboxyphenoxyacetato Dianion) Expanded by 4,4′-Bipyridine

被引：9
|
作者：
Deng, Zhao-Peng [1 ]
Huo, Li-Hua [1 ]
Gao, Shan [1 ]
Zhao, Hui [1 ]
机构：
[1] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ, Habin, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 05期
关键词：
Coordination polymers; Hydrothermal synthesis; Cadmium; 3-Carboxyphenoxyacetatic acid; Topology; HETEROGENEOUS ASYMMETRIC HYDROGENATION; POROUS COORDINATION POLYMER; REVERSIBLE SINGLE-CRYSTAL; MAGNETIC-PROPERTIES; MOLECULAR-CRYSTALS; BUILDING-BLOCKS; TRIPODAL LIGAND; GAS-ADSORPTION; WATER CLUSTERS; HYBRID SOLIDS;
D O I：
10.1002/zaac.200900374
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hydrothermal reaction of Cd(NO3) 4H(2)O with 4,4 bipyridine (bipy) and 3 carboxyphenoxyacetatic acid (3 H(2)CPOA) afforded 3D metal organic framework (MOF) [Cd(3 CPOA)(bipy)](n) 3 5nH(2)O which was characterized by elemental analyses, IR spectroscopy thermogravimetric analyses, and X ray diffraction The single crystal structural analysis revealed that It has a Cds type topological network with ID channels that contain encapsulated water molecular tapes
引用
收藏
页码：835 / 839
页数：5
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