Microwave Assisted Synthesis of Cyclic Carbonate Using Homogeneous and Heterogeneous Ionic Liquid Catalysts

被引：29
作者：
Dharman, Manju Mamparambath [1 ]
Choi, Hye-Ji [1 ]
Park, Sang-Wook [1 ]
Park, Dae-Won [1 ]
机构：
[1] Pusan Natl Univ, Dept Chem Engn, Pusan 609735, South Korea
来源：
TOPICS IN CATALYSIS | 2010年 / 53卷 / 7-10期
关键词：
Microwave; Carbon dioxide; Silica supported ionic liquid; Phenyl glycidyl ether; Cyclic carbonate; PHENYL GLYCIDYL ETHER; CYCLOHEXENE OXIDE; CO2; COPOLYMERIZATION; EPOXIDES; DIOXIDE;
D O I：
10.1007/s11244-010-9473-0
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A comparative study was effectuated between the catalytic performance of homogeneous and silica supported ionic liquids (SSILs) for the cycloaddition of epoxides and CO2 under microwave irradiation by varying the reaction parameters. Compared to the classical heating mode, both catalysts showed higher activity at moderate reaction condition through microwave irradiation.
引用
收藏
页码：462 / 469
页数：8
相关论文
共 24 条
  • [1] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities
    Arakawa, H
    Aresta, M
    Armor, JN
    Barteau, MA
    Beckman, EJ
    Bell, AT
    Bercaw, JE
    Creutz, C
    Dinjus, E
    Dixon, DA
    Domen, K
    DuBois, DL
    Eckert, J
    Fujita, E
    Gibson, DH
    Goddard, WA
    Goodman, DW
    Keller, J
    Kubas, GJ
    Kung, HH
    Lyons, JE
    Manzer, LE
    Marks, TJ
    Morokuma, K
    Nicholas, KM
    Periana, R
    Que, L
    Rostrup-Nielson, J
    Sachtler, WMH
    Schmidt, LD
    Sen, A
    Somorjai, GA
    Stair, PC
    Stults, BR
    Tumas, W
    [J]. CHEMICAL REVIEWS, 2001, 101 (04) : 953 - 996
  • [2] MICROWAVE-ASSISTED ORGANIC-REACTIONS
    CADDICK, S
    [J]. TETRAHEDRON, 1995, 51 (38) : 10403 - 10432
  • [3] Discrete metal-based catalysts for the copolymerization CO2 and epoxides:: Discovery, reactivity, optimization, and mechanism
    Coates, GW
    Moore, DR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (48) : 6618 - 6639
  • [4] Catalysts for the reactions of epoxides and carbon dioxide
    Darensbourg, DJ
    Holtcamp, MW
    [J]. COORDINATION CHEMISTRY REVIEWS, 1996, 153 : 155 - 174
  • [5] Moderate route for the utilization of CO2-microwave induced copolymerization with cyclohexene oxide using highly efficient double metal cyanide complex catalysts based on Zn3[Co(CN)6]
    Dharman, Manju Mamparambath
    Ahn, Ji-Yeon
    Lee, Mi-Kyung
    Shim, Hye-Lim
    Kim, Kyung-Hoon
    Kim, Il
    Park, Dae-Won
    [J]. GREEN CHEMISTRY, 2008, 10 (06) : 678 - 684
  • [6] THE USE OF MICROWAVE-OVENS FOR RAPID ORGANIC-SYNTHESIS
    GEDYE, R
    SMITH, F
    WESTAWAY, K
    ALI, H
    BALDISERA, L
    LABERGE, L
    ROUSELL, J
    [J]. TETRAHEDRON LETTERS, 1986, 27 (03) : 279 - 282
  • [7] Controlled microwave heating in modern organic synthesis
    Kappe, CO
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) : 6250 - 6284
  • [8] Microwave-promoted organic synthesis using ionic liquids: A mini review
    Leadbeater, NE
    Torenius, HM
    Tye, H
    [J]. COMBINATORIAL CHEMISTRY & HIGH THROUGHPUT SCREENING, 2004, 7 (05) : 511 - 528
  • [9] Synthesis of cyclic carbonate from vinyl cyclohexene oxide and CO2 using ionic liquids as catalysts
    Lee, Eun-Ha
    Ahn, Ji-Yun
    Dharman, Manju Mamparambath
    Park, Dae-Won
    Park, Sang-Wook
    Kim, Il
    [J]. CATALYSIS TODAY, 2008, 131 (1-4) : 130 - 134
  • [10] Synthesis of cyclic carbonate from allyl glycidyl ether and CO2 over silica-supported ionic liquid catalysts prepared by sol-gel method
    Lee, Mi-Kyung
    Shim, Hye-Lim
    Dharman, Manju Mamparambath
    Kim, Kyung-Hoon
    Park, Sang-Wook
    Park, Dae-Won
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2008, 25 (05) : 1004 - 1007
123