Control sonochemical parameter to prepare pure Zn0.35Fe2.65O4 nanostructures and study their photocatalytic activity

被引:413
作者
Yousefi, Seyede Rahele [1 ]
Amiri, Omid [2 ]
Salavati-Niasari, Masoud [1 ]
机构
[1] Univ Kashan, Inst Nano Sci & Nano Technol, POB 87317-51167, Kashan, Iran
[2] Univ Raparin, Coll Sci, Dept Chem, Rania, Kurdistan Regio, Iraq
基金
美国国家科学基金会;
关键词
Zn0.35Fe2.65O4; nanostructures; Ferrite; Photocatalyst; Water treatment; Sonochemistry; NICKEL FERRITE NANOPARTICLES; CATALYTIC-PROPERTIES; CARBON-MONOXIDE; ZINC FERRITE; CO; IRON; OXIDATION; DYE; DEGRADATION; PHASE;
D O I
10.1016/j.ultsonch.2019.104619
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
Zn0.35Fe2.65O4 nanostructure was prepared as a ferrite material by using a simple sonochemistry method. The effect of different parameters such as sonication time and power were studied. By increasing sonication power and time more Fe+3 ions reduced to Fe+2. This happens because H and OH radicals produced under sonication could act as a reduction agent. Therefore by increasing power and sonication time more Fe+3 ions reduced. Pure Zn0.35Fe2.65O4 nanostructure was formed when sonication time and power were 30 min and 40 W. Surface area for pure Zn0.35Fe2.65O4 nanostructure was 64 m(2).g(-1). Afterward, Zn0.35Fe2.65O4 nanostructures were applied to treat water containing different pollutants. As-prepared nanostructures degrade 60.8, 77.9, 55.2 and 44.0% of Acid Violet 7, Acid Blue 92, Acid Red 14, and Methyl Orange under visible light during 180 min irradiation. In addition, 94.5, 84.2, and 43.0% of AV7, Phil, and Ery were degraded under UV light during 120 min irradiation. The as-synthesized Zn0.35Fe2.65O4 nanostructure was characterized through the SEM, EDX, TEM, CV, DRS, BET, VSM, and XRD.
引用
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页数:14
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