Efficient Electrochemical Water Splitting Catalyzed by Electrodeposited Nickel Diselenide Nanoparticles Based Film

被引：252
作者：
Pu, Zonghua [1 ]
Luo, Yonglan [1 ]
Asiri, Abdullah M. [2 ,3 ]
Sun, Xuping [1 ]
机构：
[1] China West Normal Univ, Coll Chem & Chem Engn, Chem Synth & Pollut Control Key Lab Sichuan Prov, Nanchong 637002, Sichuan, Peoples R China
[2] King Abdulaziz Univ, Dept Chem, Jeddah 21589, Saudi Arabia
[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah 21589, Saudi Arabia
来源：
ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 07期
关键词：
electrodeposition; nickel diselenide; nanoparticles film; water splitting; hydrogen; OXYGEN EVOLUTION REACTION; IN-SITU FORMATION; NANOWIRE ARRAYS; THIN-FILM; GENERATING HYDROGEN; HIGHLY EFFICIENT; DOUBLE HYDROXIDE; OXIDE CATALYSTS; ELECTROCATALYST; METAL;
D O I：
10.1021/acsami.5b12143
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
In this contribution, we demonstrate that electrodeposited nickel diselenide nanoparticles based film on conductive Ti plate (NiSe2/Ti) is an efficient and robust electrode to catalyze both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in basic media. Electrochemical experiments show this electrode affords 10 mA cm(-2) at HER overpotential of 96 mV and 20 mA cm(-2) at OER overpotential of 295 mV with strong durability in 1.0 M KOH. The corresponding two-electrode alkaline water electrolyzer requires a cell voltage of only 1.66 V to achieve 10 mA cm(-2) water-splitting current. This development provides us an attractive non-noble-metal catalyst toward overall water splitting applications.
引用
收藏
页码：4718 / 4723
页数：6
相关论文
共 60 条
[31]   Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts [J].
Luo, Jingshan ;
Im, Jeong-Hyeok ;
Mayer, Matthew T. ;
Schreier, Marcel ;
Nazeeruddin, Mohammad Khaja ;
Park, Nam-Gyu ;
Tilley, S. David ;
Fan, Hong Jin ;
Graetzel, Michael .
SCIENCE, 2014, 345 (6204) :1593-1596
[32]   Metal-Organic Framework Derived Hybrid Co3O4-Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes [J].
Ma, Tian Yi ;
Dai, Sheng ;
Jaroniec, Mietek ;
Qiao, Shi Zhang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (39) :13925-13931
[33]   Structure-Property Relationship of Bifunctional MnO2 Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media [J].
Meng, Yongtao ;
Song, Wenqiao ;
Huang, Hui ;
Ren, Zheng ;
Chen, Sheng-Yu ;
Suib, Steven L. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (32) :11452-11464
[34]   Amorphous Molybdenum Sulfides as Hydrogen Evolution Catalysts [J].
Morales-Guio, Carlos G. ;
Hu, Xile .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (08) :2671-2681
[35]   The Artificial Leaf [J].
Nocera, Daniel G. .
ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (05) :767-776
[36]   The chemical vapor deposition of nickel phosphide or selenide thin films from a single precursor [J].
Panneerselvam, Arunkumar ;
Malik, Mohammad. A. ;
Afzaal, Mohammad ;
O'Brien, Paul ;
Helliwellt, Madeleine .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (08) :2420-2421
[37]  
Popczun E.J., 2014, ANGEW CHEMIE, V126, P5531, DOI DOI 10.1002/ANGE.201402646
[38]   Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction [J].
Popczun, Eric J. ;
McKone, James R. ;
Read, Carlos G. ;
Biacchi, Adam J. ;
Wiltrout, Alex M. ;
Lewis, Nathan S. ;
Schaak, Raymond E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (25) :9267-9270
[39]   3D macroporous MoS2 thin film: in situ hydrothermal preparation and application as a highly active hydrogen evolution electrocatalyst at all pH values [J].
Pu, Zonghua ;
Liu, Qian ;
Asiri, Abdullah M. ;
Luo, Yonglan ;
Sun, Xuping ;
He, Yuquan .
ELECTROCHIMICA ACTA, 2015, 168 :133-138
[40]   Ni2P nanoparticle films supported on a Ti plate as an efficient hydrogen evolution cathode [J].
Pu, Zonghua ;
Liu, Qian ;
Tang, Chun ;
Asiri, Abdullah M. ;
Sun, Xuping .
NANOSCALE, 2014, 6 (19) :11031-11034
123456