Dehydrogenation of amine-boranes with a frustrated Lewis pair

被引：85
作者：
Miller, Alexander J. M. [1 ]
Bercaw, John E. [1 ]
机构：
[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期
关键词：
N-HETEROCYCLIC CARBENE; AMMONIA-BORANE; METAL-FREE; CATALYTIC DEHYDROGENATION; H-2; ACTIVATION; HYDROGEN; COMPLEXES; COORDINATION; REACTIVITY; DIHYDROGEN;
D O I：
10.1039/b925659h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bulky tertiary phosphine/borane Lewis pairs (PBu3)-Bu-t/B(C6F5)(3) react with amine-boranes to afford dehydrocoupling products and phosphonium borohydride salts.
引用
收藏
页码：1709 / 1711
页数：3
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