Dehydrogenation of amine-boranes with a frustrated Lewis pair

被引：86

作者：

Miller, Alexander J. M. ^{[1
]}

Bercaw, John E. ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期

关键词：

N-HETEROCYCLIC CARBENE; AMMONIA-BORANE; METAL-FREE; CATALYTIC DEHYDROGENATION; H-2; ACTIVATION; HYDROGEN; COMPLEXES; COORDINATION; REACTIVITY; DIHYDROGEN;

D O I：

10.1039/b925659h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bulky tertiary phosphine/borane Lewis pairs (PBu3)-Bu-t/B(C6F5)(3) react with amine-boranes to afford dehydrocoupling products and phosphonium borohydride salts.

引用

页码：1709 / 1711

页数：3

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