Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged PtII-PtIV mixed-valence compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4•12H2O

被引：2

作者：

Yamashita, M

Aso, H

Matsunaga, S

Takizawa, K

Nakata, K

Kachi-Terajima, C

Iwahori, F

Ishii, T

Miyasaka, H

Sugiura, K

Kawashima, T

Takai, K

Kuroda, N

Shiro, M

Kishida, H

Okamoto, H

Takahashi, H

Tanaka, H

Marumoto, K

Kuroda, S

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Sci, Hachioji, Tokyo 1920397, Japan

[2] PRESTO, JST, Hachioji, Tokyo 1920397, Japan

[3] Nagoya Univ, Grad Sch Human Informat, Chikusa Ku, Nagoya, Aichi 4648601, Japan

[4] Kumamoto Univ, Fac Engn, Kumamoto 8608555, Japan

[5] Rigaku Co, Akishima, Tokyo 1968666, Japan

[6] Univ Tokyo, Grad Sch Frontier Sci, Bunkyo Ku, Tokyo 1138656, Japan

[7] PRESTO, JST, Bunkyo Ku, Tokyo 1138656, Japan

[8] Nagoya Univ, Dept Appl Phys, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 03期

关键词：

D O I：

10.1246/cl.2003.278

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of complex consisting of double liner-chain structure {[Pt(en)(2)][PtCl2(en)(2)]}(3)(CuCl4)(4) . 12H(2)O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (Pt-III component) formation was found. This unprecedented soliton formation mechanism will be discussed.

引用

页码：278 / 279

页数：2

共 21 条

[1]

ASO T, 2002, MOL CRYST LIQ CRYST, V7, P376

[2]

Bishop A. R., 1993, LOS ALAMOS SCI, V21, P133

[3] ELECTRONIC AND RESONANCE-RAMAN SPECTRA OF THE LINEAR-CHAIN MIXED-VALENCE PLATINUM COMPLEXES ([PT(EN)2][PT(EN)2X2])3[CUX4]4 [X=CL (1) OR BR (2)] AND [PT(PN)2][PT(PN)BR2][CU3BR5]2 (3) (EN = ETHANE-1,2-DIAMINE AND PN = PROPANE-1,2-DIAMINE) [J].