An arene-ruthenium(II) complex containing novel hybrid phosphinofluoro ligands

被引：5
|
作者：
Yao, WR [1 ]
Liu, ZH [1 ]
Zhang, QF [1 ]
机构：
[1] Anhui Univ Technol, Dept Chem & Chem Engn, Anhui 243002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S0108270103005808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, (eta(6)-p-cymene)[(diphenylphosphinofluorido)trifluoroborato-kappa(2)P,F][(diphenylphosphinoylfluorido) trifluoroborato-kappaO]ruthenium(II), [Ru(C12H10BF4OP)(C12H10BF4P)(C10H14)], the hybrid Ph2PFBF3 ligand is bidentate (kappa(2)P,F) and thus forms a five-membered chelate ring. The Ph2PFBF3 ligand is unusually ligated to the metal through the P atom of the PPh2 moiety and through one of the F atoms of the BF4 moiety. The phosphine-oxidized Ph2P(O)FBF3 ligand is bonded to the Ru atom via the O atom. The Ru centre has a pseudo-octahedral coordination environment, in which the phenyl ring occupies three of the corners of the distorted octahedron. The Ru-O, Ru-F and Ru-P bond lengths are 2.107 (3), 2.135 (4) and 2.3145 (15) Angstrom, respectively.
引用
收藏
页码：M156 / M158
页数：3
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