catena-Poly[[[bis(μ-4-cyanobenzoato-κ2O:O)-bis[(4-cyanobenzoato-κ2O,O′)cobalt(II)]]-di-μ-4,4′-bipyridine-κ4N:N′] dihydrate dimethylformamide tetrasolvate]

被引:6
作者
He, HY
Zhu, LG [1 ]
Ng, SW
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310007, Peoples R China
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
关键词
D O I
10.1107/S1600536805001054
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, {[Co-2(C8H4NO2) (4)(C10H8N2)(2)] . 2H(2)O . 4C(3)H(7)NO}(n), features a centrosymmetric eight-membered - Co - O - C - O - Co - O - C - O-ring that arises from the bridging of two Co atoms by two cyanobenzoate units across a center of symmetry. Each Co atom is also chelated by a cyanobenzoate unit and the two remaining coordination sites, trans to each other in the distorted octahedron, are occupied by the N atoms of the heterocycle, resulting in a polymeric ribbon structure. The water and dimethylformamide molecules occupy the space between the chains.
引用
收藏
页码:M311 / M313
页数:3
相关论文
共 8 条
[1]   Bis(2,2′-bipyridine)(3-carboxy-4-hydroxybenzenesulfonato)copper(II) 3-carboxy-4-hydroxybenzenesulfonate [J].
Gao, S ;
Huo, LH ;
Zhao, H ;
Ng, SW .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M290-M292
[2]   Poly[[diaquacobalt(II)]-di-μ-4-cyanobenzoato-κ4O:O′] [J].
He, HY ;
Chen, J ;
Wang, XH ;
Zhu, LG .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 :M540-M542
[3]   Diaqua(4,4′-bipyridine)bis(4-cyanobenzoato)cobalt(II) [J].
He, HY ;
Ma, AQ ;
Zhu, LG .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M333-M335
[4]  
Higashi T., 1995, ABSCOR
[5]  
JOHNSON CK, 1976, ORNL 5138
[6]  
*RIG CORP, 1998, RAPID AUTO
[7]  
*RIG MSC INC, 2002, CRYSTALSTRUCTURE
[8]  
Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination