共 551 条
Mixed matrix proton exchange membranes for fuel cells: State of the art and perspectives
被引:270
作者:
Bakangura, Erigene
[1
]
Wu, Liang
[1
]
Ge, Liang
[1
]
Yang, Zhengjin
[1
]
Xu, Tongwen
[1
]
机构:
[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Lab Funct Membranes, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Proton exchange membranes;
Fuel cell;
Proton transport;
Mixed matrix;
Advanced materials;
POLYMER ELECTROLYTE MEMBRANES;
POLY(ARYLENE ETHER SULFONE);
NAFION COMPOSITE MEMBRANES;
LOW-METHANOL-PERMEABILITY;
METAL-ORGANIC FRAMEWORKS;
HIGH-TEMPERATURE OPERATION;
HIGH-SURFACE-AREA;
ZIRCONIUM-PHOSPHATE SULFOPHENYLENPHOSPHONATES;
POLY(PHENYLENE OXIDE) MEMBRANES;
POROUS COORDINATION POLYMERS;
D O I:
10.1016/j.progpolymsci.2015.11.004
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Proton-conducting mixed matrix membranes (PC-MMMs) have received considerable interest as promising materials that combine the properties of, and create synergism from interactions between, polymeric and inorganic components. The PC-MMM exhibit superior characteristics compared to individual ion-conducting polymeric membranes or free-standing electrolyte inorganic films. Recent advancements in material preparation have enhanced the ability to design PC-MMMs with specified properties. This critical review discusses the progress of the development of PC-MMMs, with special focus on PC-MMMs based on emerging materials, such as porous materials, metal organic frameworks (MOFs), carbon nanotubes (CNTs) and graphene oxides (GOs). Major challenges facing PC-MMMs and strategies taken to overcome those challenges and future perspectives are discussed. (c) 2016 Elsevier Ltd. All rights reserved.
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页码:103 / 152
页数:50
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