Mixed matrix proton exchange membranes for fuel cells: State of the art and perspectives

被引:270
作者
Bakangura, Erigene [1 ]
Wu, Liang [1 ]
Ge, Liang [1 ]
Yang, Zhengjin [1 ]
Xu, Tongwen [1 ]
机构
[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Lab Funct Membranes, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
Proton exchange membranes; Fuel cell; Proton transport; Mixed matrix; Advanced materials; POLYMER ELECTROLYTE MEMBRANES; POLY(ARYLENE ETHER SULFONE); NAFION COMPOSITE MEMBRANES; LOW-METHANOL-PERMEABILITY; METAL-ORGANIC FRAMEWORKS; HIGH-TEMPERATURE OPERATION; HIGH-SURFACE-AREA; ZIRCONIUM-PHOSPHATE SULFOPHENYLENPHOSPHONATES; POLY(PHENYLENE OXIDE) MEMBRANES; POROUS COORDINATION POLYMERS;
D O I
10.1016/j.progpolymsci.2015.11.004
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Proton-conducting mixed matrix membranes (PC-MMMs) have received considerable interest as promising materials that combine the properties of, and create synergism from interactions between, polymeric and inorganic components. The PC-MMM exhibit superior characteristics compared to individual ion-conducting polymeric membranes or free-standing electrolyte inorganic films. Recent advancements in material preparation have enhanced the ability to design PC-MMMs with specified properties. This critical review discusses the progress of the development of PC-MMMs, with special focus on PC-MMMs based on emerging materials, such as porous materials, metal organic frameworks (MOFs), carbon nanotubes (CNTs) and graphene oxides (GOs). Major challenges facing PC-MMMs and strategies taken to overcome those challenges and future perspectives are discussed. (c) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:103 / 152
页数:50
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