C-H Bond Activations by Metal Oxo Compounds

被引：467

作者：

Gunay, Ahmet ^{[1
]}

Theopold, Klaus H. ^{[1
]}

机构：

[1] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

CHEMICAL REVIEWS | 2010年 / 110卷 / 02期

关键词：

SOLUBLE METHANE MONOOXYGENASE; HYDROGEN-ATOM ABSTRACTION; OXIDATIVE N-DEALKYLATION; METHYLOSINUS-TRICHOSPORIUM OB3B; METHYLOCOCCUS-CAPSULATUS-BATH; CLOCK SUBSTRATE PROBES; ELECTRON-TRANSFER; HYDRIDE TRANSFER; 9-SUBSTITUTED 10-METHYL-9,10-DIHYDROACRIDINES; SPECTROSCOPIC CHARACTERIZATION;

D O I：

10.1021/cr900269x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to demonstrate C-H bond activations by metal oxo compounds. The latest developments helped in investigating metal oxo mediated C-H bond functionalizations. Investigations revealed that linear energy relationships, such as that existing between C-H bond strength and the rate constant for hydrogen atom abstraction were applied to these reactions. It was also recognized at the same time that metal complexes were more flexible and varied in their electronic structure than a simple monatomic radical.

引用

页码：1060 / 1081

页数：22

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