Chiral Bioinspired Plasmonics: A Paradigm Shift for Optical Activity and Photochemistry

被引：43

作者：

Avalos-Ovando, Oscar ^{[1
,2
,3
]}

Santiago, Eva Yazmin ^{[2
,3
]}

Movsesyan, Artur ^{[1
,2
,3
]}

Kong, Xiang-Tian ^{[4
]}

Yu, Peng ^{[1
,5
]}

Besteiro, Lucas, V ^{[6
]}

Khorashad, Larousse Khosravi ^{[7
]}

Okamoto, Hiromi ^{[8
,9
]}

Slocik, Joseph M. ^{[10
]}

Correa-Duarte, Miguel A. ^{[6
]}

Comesana-Hermo, Miguel ^{[11
]}

Liedl, Tim ^{[12
,13
]}

Wang, Zhiming ^{[1
,14
]}

Markovich, Gil ^{[15
]}

Burger, Sven ^{[16
,17
]}

Govorov, Alexander O. ^{[2
,3
]}

机构：

[1] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Peoples R China

[2] Ohio Univ, Dept Phys & Astron, Athens, OH 45701 USA

[3] Ohio Univ, Nanoscale & Quantum Phenomena Inst, Athens, OH 45701 USA

[4] Nankai Univ, Sch Phys, Tianjin 300071, Peoples R China

[5] Chengdu Univ Informat Technol, Coll Optoelect Technol, Chengdu 610225, Peoples R China

[6] Univ Vigo, CINBIO, Vigo 36310, Spain

[7] Univ Nebraska, Dept Elect & Comp Engn, Lincoln, NE 68588 USA

[8] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[9] Grad Univ Adv Studies SOKENDAI, Okazaki, Aichi 4448585, Japan

[10] Air Force Res Lab, Soft Matter Mat Branch, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA

[11] Univ Paris, ITODYS, CNRS, F-75013 Paris, France

[12] Ludwig Maximilians Univ Munchen, Fac Phys, D-80539 Munich, Germany

[13] Ludwig Maximilians Univ Munchen, Ctr NanoSci CeNS, D-80539 Munich, Germany

[14] Chengdu Univ, Inst Adv Study, Chengdu 610106, Peoples R China

[15] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-6997801 Tel Aviv, Israel

[16] Zuse Inst Berlin, D-14195 Berlin, Germany

[17] JCMwave GmbH, D-14050 Berlin, Germany

来源：

ACS PHOTONICS | 2022年 / 9卷 / 07期

基金：

日本学术振兴会; 中国国家自然科学基金; 欧洲研究理事会;

关键词：

chiral plasmonics; chiral nanocrystals; bioassembly; photochemistry; circular dichroism; DNA origami; CIRCULAR-DICHROISM; NANOPARTICLE ASSEMBLIES; NANOCRYSTALS; NANOSTRUCTURES; SUPERSTRUCTURES;

D O I：

10.1021/acsphotonics.2c00445

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This Perspective concerns the latest developments in the field of chiral nanocrystals (NCs) and metastructures, focusing primarily on plasmonic nanostructures. Such nanomaterials exhibit unusually strong near-field and electromagnetic responses that enable efficient biosensing and light manipulation. Herein we share our thoughts on the latest trends that mark what we call a paradigm shift for the vast and dynamic field of chiroptical materials. The topics to be considered include polarization-sensitive photocatalysis with chiral plasmonic NCs, chiral bioconjugates, DNA-based assemblies, chiral growth, and we also describe the fundamental challenges for optical induction of chirality, transfer of chirality between different scales, and theoretical issues that nanoscience is facing.

引用

页码：2219 / 2236

页数：18

共 90 条

[1] Induced Chirality through Electromagnetic Coupling between Chiral Molecular Layers and Plasmonic Nanostructures [J].