MINERALOGICAL AND GEOCHEMICAL CHARACTERIZATION OF CAN VOLCANICS AND RELEATED KAOLIN DEPOSITS, CANAKKALE, TURKEY

被引:0
作者
Ercan, Hatice Unal [1 ]
Ece, O. Isik [1 ]
Karacik, Zekiye [1 ]
机构
[1] Istanbul Tech Univ, Dept Geol Engn, Istanbul, Turkey
来源
GEOCONFERENCE ON SCIENCE AND TECHNOLOGIES IN GEOLOGY, EXPLORATION AND MINING, SGEM 2013, VOL I | 2013年
关键词
Biga Peninsula; kaolin; alunite; stable isotopes; geochemistry; PORPHYRY; ANATOLIA;
D O I
暂无
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
The Saribeyli - Sigirli and Bodurlar kaolin deposits (Canakkale) are hosted by andesitic tuffs of the Oligocene volcanic rocks. can volcanis are classified as andesite, basaltic-andesite and basaltic-trachy andesite and tuffs can be classified as andesite and rhyolite. Saribeyli-Sigirli kaolin deposit exposes the following mineral zonations from the fault zone to the outer; i) quartz, ii) alunite +/- quartz +/- kaolinite +/- dickite, iii) kaolinite +/- dickite +/- alunite +/- quartz and iv) kaolinite +illite +feldspar, respectively. Bodurlu kaolin deposit exposes the following mineral zonations from the fault zone to the outer; i) quartz +/- Feoxides +/- alunite +/- jarosite and ii) kaolinite +/- halloysite +/- illite +/- quartz +/- feldspar, respectively. The N30 degrees W trending two faults passes through the north and south boundaries of kaolin quarry and four quarries have been operating inside the small scale graben. Fault zones pass through inside the Bodurlu quarry exhibit a group of six parallel fracture systems rather than single fault zone and kaolinization occurred between and vicinity of these fracture systems. Based on FE-SEM studies, micro-morphologic features of kaolinite crystals show that kaolinite occurs as hexagonal blocky and book-shaped kaolinite which forms as ordered and disordered crystals. Halloysite habits are parallel and randomly non-parallel sticks. The delta S-34 values of Saribeyli-Sigirli deposits range from +4.1 to +2.4 %o and these values reflect its formation from magmatic-hydrothermal derived sulfur source. The delta O-18 and delta D values in these deposits range from + 6.7 to + 12.7 %o and from -61 to -97 parts per thousand, respectively, which are very close the line of primitive magmatic water. Isotopes data suggest that original geothermal waters were the mixture of magmatic water and meteoric waters. O-and H-isotopic values of the Bodurlu kaolin deposit are between delta O-18 +14.5 / +17 %o and for delta D -90 / 99 parts per thousand, which data reflect genesis of supergene origin and enriched regarding of delta O-18 values. According to mineralogical, geochemical and S-O-H data, these deposits were occurred by the ascending acidic geothermal waters through fault zones in the shallow epithermal systems, which are rich in kaolinite minerals. These steam-heated environments including hot-water outlets, H2S enriched vapor and groundwater mixed in the vadose zone. These hypogene origin H2SO4 rich geothermal fluids cooled and oxidized when they mixed with cold groundwater when they reached to the surface through fault systems.
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页码:121 / 128
页数:8
相关论文
共 22 条
  • [1] Collision-driven slab breakoff magmatism in northwestern Anatolia, Turkey
    Altunkaynak, Safak
    [J]. JOURNAL OF GEOLOGY, 2007, 115 (01) : 63 - 82
  • [2] Dayal A, 1984, THESIS DOKUZ EYLUL U
  • [3] Dill H.G., 1997, Z ANGEW GEOL, V43, P198
  • [4] Mineralogical and chemical studies of volcanic-related argillaceous industrial minerals of the Central American Cordillera (western El Salvador)
    Dill, HG
    Bosse, HR
    Kassbohm, J
    [J]. ECONOMIC GEOLOGY AND THE BULLETIN OF THE SOCIETY OF ECONOMIC GEOLOGISTS, 2000, 95 (03): : 517 - 538
  • [5] Ercan T., 1979, Jeoloji Muhendisligi Dergisi, V9, P23
  • [6] Gene S. C., 1995, TECTONOPHYSICS, V243, P193
  • [7] D-H evidence for the timing of kaolinization in Northeast Bavaria, Germany
    Gilg, HA
    [J]. CHEMICAL GEOLOGY, 2000, 170 (1-4) : 5 - 18
  • [8] Evolution of an intrusion-centered hydrothermal system: Far Southeast-Lepanto porphyry and epithermal Cu-Au deposits, Philippines
    Hedenquist, JW
    Arribas, A
    Reynolds, TJ
    [J]. ECONOMIC GEOLOGY AND THE BULLETIN OF THE SOCIETY OF ECONOMIC GEOLOGISTS, 1998, 93 (04): : 373 - 404
  • [9] Krushensky R., 1976, Bulletin Volcanologique, V40, P336
  • [10] Le Maitre R.W., 2005, Igneous rocks: a classification and glossary of terms: recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks