Highly stable cage-like complexes by self-assembly of tetracationic Zn(II) porphyrinates and tetrasulfonatocalix[4]arenes in polar solvents

被引：68

作者：

Fiammengo, R ^{[1
]}

Timmerman, P ^{[1
]}

de Jong, F ^{[1
]}

Reinhoudt, DN ^{[1
]}

机构：

[1] MESA Res Inst, Lab Supramol Chem & Technol, NL-7500 AE Enschede, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 23期

关键词：

D O I：

10.1039/b006960o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetracationic Zn(II) porphyrinates and tetraanionic calix[4]arenes can be assembled in polar solvents to obtain cage-like complexes in an entropy driven process. These structures are remarkably stable even in the presence of water or competing salts.

引用

页码：2313 / 2314

页数：2

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