Transition-Metal-Mediated Cleavage of C-C Bonds in Aromatic Rings

被引：14

作者：

Jakoobi, Martin ^{[1
]}

Sergeev, Alexey G. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 13期

关键词：

arene ligands; arenes; C-C activation; cleavage reactions; cyclopentadienyl ligands; transition metals; CARBON-CARBON BOND; HETEROCYCLIC CARBENE LIGAND; SELECTIVE ARENE CLEAVAGE; ARYL SUBSTITUENT; BENZENE; ACTIVATION; INSERTION; MECHANISM; CONTRACTION; COMPLEXES;

D O I：

10.1002/asia.201900443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-mediated cleavage of aromatic C-C bonds has a range of potential synthetic applications: from direct coal liquefaction to synthesis of natural products. However, in contrast to the activation of aromatic C-H bonds, which has already been widely studied and exploited in diverse set of functionalization reactions, cleavage of aromatic C-C bonds remains Terra incognita. This Minireview summarizes the recent progress in this field and outlines key challenges to be overcome to develop synthetic methods based on this fundamental organometallic transformation.

引用

页码：2181 / 2192

页数：12

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