Metal-ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

被引：138
作者：
Kuwata, Shigeki [1 ]
Ikariya, Takao [1 ]
机构：
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 152, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 92期
关键词：
PYRIDINE-BASED TRIDENTATE; C-H ACTIVATION; TRANSFER HYDROGENATION; 2-SUBSTITUTED PYRIDINES; RUTHENIUM(II) COMPLEXES; INTRAMOLECULAR HYDROAMINATION; IRON(II) COMPLEXES; BOND ACTIVATION; COORDINATION CHEMISTRY; IRIDIUM(III) COMPLEXES;
D O I：
10.1039/c4cc04457f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-ligand bifunctional cooperation has attracted much attention because it offers a powerful methodology to realize a number of highly efficient and selective catalysts. In this article, recent developments in the metal-ligand cooperative reactions of protic N-heterocyclic carbene (NHC) and pyrazole complexes bearing an acidic NH group at the position beta to the metal are surveyed. Protic 2-pyridylidenes as related cooperating non-innocent ligands are also described.
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收藏
页码：14290 / 14300
页数：11
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