Rapid Room-Temperature Synthesis of Cu3(BTC)2 Crystals in Water

被引：5
|
作者：
Na, Liyan [1 ]
Zhang, Liying [1 ]
Zhang, Wei [1 ]
Hua, Ruinian [1 ]
机构：
[1] Dalian Nationalities Univ, Coll Life Sci, Dalian, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 10期
基金：
中国国家自然科学基金;
关键词：
metal-organic frameworks; porous materials; room temperature; characterization; METAL-ORGANIC FRAMEWORK; COORDINATION POLYMERS; PARTICLES; EFFICIENT; SIZE;
D O I：
10.1080/15533174.2013.862700
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this article, a new process for the synthesis of metal-organic framework (MOF) particles that uses water as the only solvent is presented. High-quality Cu-3(BTC)(2) (BTC D 1,3,5-benzenetricarboxylate) crystals were obtained via a facile and environmentally benign route in water at room temperature by directly mixing aqueous solutions of Cu(NO3)(2) and the methylammonium salt of H3BTC. By adjusting the concentrations of the two reactants, we could obtain polyhedral crystals (500-1000nm), micro rods (15 x 3 mu m) with hierarchical structures and rods (10 x 1 mu m) with smooth surfaces. X-ray diffractions and gas sorption measurements revealed highly crystalline particles with large BET surface areas and total pore volumes.
引用
收藏
页码：1463 / 1466
页数：4
相关论文
共 50 条
  • [31] Cu3(BTC)2: CO oxidation over MOF based catalysts
    Ye, Jing-yun
    Liu, Chang-jun
    CHEMICAL COMMUNICATIONS, 2011, 47 (07) : 2167 - 2169
  • [32] Heteropolyacid encapsulated in Cu3(BTC)2 nanocrystals: An effective esterification catalyst
    Wee, Lik H.
    Janssens, Nikki
    Bajpe, Sneha R.
    Kirschhock, Christine E. A.
    Martens, Johan A.
    CATALYSIS TODAY, 2011, 171 (01) : 275 - 280
  • [33] Room-Temperature Synthesis of Pyr1/3 @Cu-BTC with Enhanced Stability and Its Excellent Performance for Separation of Propylene/Propane
    Sun, Yiwei
    Ke, Zhanfan
    Tang, Yuning
    Wang, Sa
    Wu, Ying
    Xia, Qibin
    Li, Zhong
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (13) : 6202 - 6209
  • [34] First In Situ NMR Observation of Hydrogen Adsorbed inside [Cu3(btc)2] at Ambient Temperature and Pressure
    Dekura, Shun
    Kobayashi, Hirokazu
    Li, Guangqin
    Ikeda, Ryuichi
    Kubota, Yoshiki
    Takata, Masaki
    Kitagawa, Hiroshi
    CHEMISTRY LETTERS, 2014, 43 (08) : 1363 - 1364
  • [35] Study of mechanochemical synthesis in the formation of the metal-organic framework Cu3(BTC)2 for hydrogen storage
    Yang, Hongwei
    Orefuwa, Samuel
    Goudy, Andrew
    MICROPOROUS AND MESOPOROUS MATERIALS, 2011, 143 (01) : 37 - 45
  • [36] NO adsorption in amino-modified Cu3(btc)2-type MOFs studied by solid-state NMR
    Khan, Arafat Hossain
    Peikert, Katharina
    Froeba, Michael
    Bertmer, Marko
    MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 216 : 111 - 117
  • [37] Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework
    Cravillon, Janosch
    Muenzer, Simon
    Lohmeier, Sven-Jare
    Feldhoff, Armin
    Huber, Klaus
    Wiebcke, Michael
    CHEMISTRY OF MATERIALS, 2009, 21 (08) : 1410 - 1412
  • [38] Ammonia Vapor Removal by Cu3(BTC)2 and Its Characterization by MAS NMR
    Peterson, Gregory W.
    Wagner, George W.
    Balboa, Alex
    Mahle, John
    Sewell, Tara
    Karwacki, Christopher J.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (31) : 13906 - 13917
  • [39] Flexible Cu3(HHTP)2 MOF Membranes for Gas Sensing Application at Room Temperature
    Ali, Ashraf
    AlTakroori, Husam H. D.
    Greish, Yaser E.
    Alzamly, Ahmed
    Siddig, Lamia A.
    Qamhieh, Naser
    Mahmoud, Saleh T.
    NANOMATERIALS, 2022, 12 (06)
  • [40] Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina
    Gascon, Jorge
    Aguado, Sonia
    Kapteijn, Freek
    MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 113 (1-3) : 132 - 138
12345