Large-Scale Growth of Nitrogen-Doped Via Solvothermal Synthesis

被引：2

作者：

Chen, Xianlan ^{[1
]}

Wu, Na ^{[1
]}

Gou, Gaozhang ^{[1
]}

Shi, Ling ^{[1
]}

Pan, Shanqin ^{[1
]}

Liu, Wei ^{[1
]}

机构：

[1] Honghe Univ, Sch Sci, Yunnan 661100, Peoples R China

来源：

APPLIED MECHANICS, MATERIALS AND MANUFACTURING IV | 2014年 / 670-671卷

关键词：

N-doped graphene; solvothermal synthesis; urea; XPS analysis; GRAPHENE OXIDE;

D O I：

10.4028/www.scientific.net/AMM.670-671.323

中图分类号：

TH [机械、仪表工业];

学科分类号：

0802 ;

摘要：

Theoretical studies predicted that doping graphene with nitrogen can tailor its electronic properties and chemical reactivity. We develop here a novel method for synthesis N-doped graphene via solvothermal synthesis process with urea as both reductant and nitrogen sources. The resulting N-doped graphene were characterized by various methods (UV-vis spectra, SEM and XPS). XPS analysis shows a predominant graphitic C 1s peak at ca. 285 eV, an O 1s peak at ca. 532 eV and N 1s peak at ca. 410 eV. Moreover, the atomic ratio of N/ C is 5.0% for N-doped graphene, demonstrating nitrogen species have been successfully incorporated into N-doped graphene.

引用

页码：323 / 326

页数：4

共 10 条

[1] PREPARATION OF GRAPHITIC OXIDE [J].

HUMMERS, WS ;

OFFEMAN, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339

[2] Nitrogen-Doped Graphene Quantum Dots with Oxygen-Rich Functional Groups [J].

Li, Yan ;

Zhao, Yang ;

Cheng, Huhu ;

Hu, Yue ;

Shi, Gaoquan ;

Dai, Liming ;

Qu, Liangti .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :15-18

[3] Palladium Nanoparticles Embedded into Graphene Nanosheets: Preparation, Characterization, and Nonenzymatic Electrochemical Detection of H2O2 [J].

Liu, Hongfang ;

Chen, Xianlan ;

Huang, Linhong ;

Wang, Jian ;

Pan, Haibo .

ELECTROANALYSIS, 2014, 26 (03) :556-564

[4] Synthesis, Structure, and Properties of Boron- and Nitrogen-Doped Graphene [J].

Panchokarla, L. S. ;

Subrahmanyam, K. S. ;

Saha, S. K. ;

Govindaraj, Achutharao ;

Krishnamurthy, H. R. ;

Waghmare, U. V. ;

Rao, C. N. R. .

ADVANCED MATERIALS, 2009, 21 (46) :4726-+

[5] Graphene oxide dispersions in organic solvents [J].

Paredes, J. I. ;

Villar-Rodil, S. ;

Martinez-Alonso, A. ;

Tascon, J. M. D. .

LANGMUIR, 2008, 24 (19) :10560-10564

[6] High performance supercapacitors based on highly conductive nitrogen-doped graphene sheets [J].

Qiu, Yongcai ;

Zhang, Xinfeng ;

Yang, Shihe .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (27) :12554-12558

[7] Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells [J].

Qu, Liangti ;

Liu, Yong ;

Baek, Jong-Beom ;

Dai, Liming .

ACS NANO, 2010, 4 (03) :1321-1326

[8] Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage [J].

Sun, Li ;

Wang, Lei ;

Tian, Chungui ;

Tan, Taixing ;

Xie, Ying ;

Shi, Keying ;

Li, Meitong ;

Fu, Honggang .

RSC ADVANCES, 2012, 2 (10) :4498-4506

[9] Synthesis of Nitrogen-Doped Graphene Using Embedded Carbon and Nitrogen Sources [J].

Zhang, Chaohua ;

Fu, Lei ;

Liu, Nan ;

Liu, Minhao ;

Wang, Yayu ;

Liu, Zhongfan .

ADVANCED MATERIALS, 2011, 23 (08) :1020-1024

[10] Tin Nanoparticles Impregnated in Nitrogen-Doped Graphene for Lithium-Ion Battery Anodes [J].

Zhou, Xiaosi ;

Bao, Jianchun ;

Dai, Zhihui ;

Guo, Yu-Guo .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (48) :25367-25373

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