Solute effects on interfacial dislocation emission in nanomaterials: Nucleation site competition and neutralization

被引:20
作者
Borovikov, Valery [1 ]
Mendelev, Mikhail I. [1 ]
King, Alexander H. [1 ,2 ]
机构
[1] Ames Lab, Div Mat Sci & Engn, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
关键词
Solute segregation at grain boundaries; Dislocation nucleation; Yield stress; Monte Carlo simulation; Molecular dynamics simulation; GRAIN-BOUNDARY SEGREGATION; NANOCRYSTALLINE ALLOYS; MOLECULAR-DYNAMICS; STRENGTH; CU; SIZE; MAXIMUM; METALS; DESIGN; COPPER;
D O I
10.1016/j.scriptamat.2018.05.011
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Solutes added to stabilize nano-crystalline metals against grain growth, may segregate to grain boundaries and triple junctions where they can affect the process of the dislocation emission. We demonstrate that this effect can be very complex due to different rates of segregation at different interfaces. Moreover, at large concentrations, when the solutes form clusters, the interfaces between these clusters and the matrix can introduce new dislocation emission sources, which can be activated under lower applied stress. Thus, the strength maximum can occur at a certain solute concentration: adding solutes beyond this optimal concentration can reduce the strength of the material. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:12 / 15
页数:4
相关论文
共 30 条
[1]   The strongest size [J].
Argon, A. S. ;
Yip, S. .
PHILOSOPHICAL MAGAZINE LETTERS, 2006, 86 (11) :713-720
[2]   Effects of solutes on dislocation nucleation from grain boundaries [J].
Borovikov, Valery ;
Mendelev, Mikhail I. ;
King, Alexander H. .
INTERNATIONAL JOURNAL OF PLASTICITY, 2017, 90 :146-155
[3]   Effects of Schmid factor and slip nucleation on deformation mechanism in columnar-grained nanotwinned Ag and Cu [J].
Borovikov, Valery ;
Mendelev, Mikhail I. ;
King, Alexander H. ;
LeSar, Richard .
JOURNAL OF APPLIED PHYSICS, 2015, 117 (08)
[4]   Texture of Nanocrystalline Nickel: Probing the Lower Size Limit of Dislocation Activity [J].
Chen, Bin ;
Lutker, Katie ;
Raju, Selva Vennila ;
Yan, Jinyuan ;
Kanitpanyacharoen, Waruntorn ;
Lei, Jialin ;
Yang, Shizhong ;
Wenk, Hans-Rudolf ;
Mao, Ho-kwang ;
Williams, Quentin .
SCIENCE, 2012, 338 (6113) :1448-1451
[5]   Hardness and strain rate sensitivity of nanocrystalline Cu [J].
Chen, J ;
Lu, L ;
Lu, K .
SCRIPTA MATERIALIA, 2006, 54 (11) :1913-1918
[6]   Design of Stable Nanocrystalline Alloys [J].
Chookajorn, Tongjai ;
Murdoch, Heather A. ;
Schuh, Christopher A. .
SCIENCE, 2012, 337 (6097) :951-954
[7]   Tailoring and patterning the grain size of nanocrystalline alloys [J].
Detor, Andrew J. ;
Schuh, Christopher A. .
ACTA MATERIALIA, 2007, 55 (01) :371-379
[8]   NANOCRYSTALLINE MATERIALS [J].
BIRRINGER, R .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1989, 117 :33-43
[9]   MOLECULAR-DYNAMICS STUDY OF MELTING AND FREEZING OF SMALL LENNARD-JONES CLUSTERS [J].
HONEYCUTT, JD ;
ANDERSEN, HC .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (19) :4950-4963
[10]   METALLURGY Grain boundary stability governs hardening and softening in extremely fine nanograined metals [J].
Hu, J. ;
Shi, Y. N. ;
Sauvage, X. ;
Sha, G. ;
Lu, K. .
SCIENCE, 2017, 355 (6331) :1292-+