Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity

被引：19

作者：

Shao, Kai ^{[1
]}

Pei, Jiyan ^{[1
]}

Wang, Jia-Xin ^{[1
]}

Yang, Yu ^{[1
]}

Cui, Yuanjing ^{[1
]}

Zhou, Wei ^{[2
]}

Yildirim, Taner ^{[2
]}

Li, Bin ^{[1
]}

Chen, Banglin ^{[3
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China

[2] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[3] Univ Texas San Antonio, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 76期

基金：

中国国家自然科学基金;

关键词：

GAS-STORAGE; ADSORPTION; MOFS; CH4;

D O I：

10.1039/c9cc06239d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm(3) (STP) cm(-3) at 298 K and 5-80 bar.

引用

页码：11402 / 11405

页数：4

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