Sulfonated Poly(ether ether ketone)-Induced Porous Poly(ether sulfone) Blend Membranes for the Separation of Proteins and Metal Ions

Asymmetric ultrafiltration (UF) membranes were prepared by the blending of poly(ether sulfone) (PES) and sulfonated poly(ether ether ketone) (SPEEK) polymers with N,N'-dimethylformamide solvent by the phase-inversion method. SPEEK was selected as the hydrophilic polymer in a blend with different composition of PES and SPEEK. The solution-cast PES/SPEEK blend membranes were homogeneous for all of the studied compositions from 100/0 to 60/40 wt % in a total of 17.5 wt % polymer and 82.5 wt % solvent. The presence of SPEEK beyond 40 wt % in the casting solution did not form membranes. The prepared membranes were characterized for their UF performances, such as pure water flux, water content, porosity, and membrane hydraulic resistance, and morphology and melting temperature. We estimated that the pure water flux of the PES/SPEEK blend membranes increased from 1.7.3 to 85.6 L m(-2) h(-1) when the concentration of SPEEK increased from 0 to 40 wt% in the casting solution. The membranes were also characterized their separation performance with proteins and metal-ion solutions. The results indicate significant improvement in the performance characteristics of the blend membranes with the addition of SPEEK. In particular, the rejection of proteins and metal ions was marginally decreased, whereas the permeate flux was radically improved. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 116:995-1004, 2010