A hydridoirida-β-diketone as an efficient and robust homogeneous catalyst for the hydrolysis of ammonia-borane or amine-borane adducts in air to produce hydrogen

被引：31

作者：

Ciganda, Roberto ^{[1
]}

Garralda, Maria A. ^{[1
]}

Ibarlucea, Lourdes ^{[1
]}

Pinilla, Elena ^{[2
]}

Rosario Torres, M. ^{[2
]}

机构：

[1] Univ Basque Country, Fac Quim San Sebastian, San Sebastian 20080, Spain

[2] Univ Complutense, Dept Quim Inorgan, Lab Difracc Rayos 10, Fac Ciencias Quim, E-28040 Madrid, Spain

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 31期

关键词：

DEHYDROGENATION; GENERATION; COMPLEXES; BOROHYDRIDE; CARBENE; METALS;

D O I：

10.1039/c0dt00091d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first homogeneous metal-catalysed hydrolysis of ammonia-borane or amine-borane adducts for hydrogen generation, using a stable organometallic complex[IrHCl{(PPh2(o-C6H4CO))(2)H}], is reported.

引用

页码：7226 / 7229

页数：4

共 44 条

[1] Novel hydridoirida-β-diketones containing small molecules, CO, or ethylene:: Their behavior in coordinating solvents such as dimethylsulfoxide or acetonitrile [J].

Acha, F ;

Garralda, MA ;

Ibarlucea, L ;

Pinilla, E ;

Torres, MR .

INORGANIC CHEMISTRY, 2005, 44 (24) :9084-9091

[2] Reactivity of hydridoirida-β-diketones with bases:: the selective formation of new di-μ-acyl-μ-hydridodiiridium(III) or dihydridoirida-β-diketone complexes and heterometallic Ir(III)-Rh(I) derivatives [J].

Acha, Francisco ;

Ciganda, Roberto ;

Garralda, Maria A. ;

Hernandez, Ricardo ;

Ibarlucea, Lourdes ;

Pinilla, Elena ;

Torres, M. Rosario .

DALTON TRANSACTIONS, 2008, (34) :4602-4611

[3] Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes [J].

Blaquiere, Nicole ;

Diallo-Garcia, Sarah ;

Gorelsky, Serge I. ;

Black, Daniel A. ;

Fagnou, Keith .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14034-+

[4]

*BRUK SIEM AN XRAY, 1998, SHELXTL V 5 1

[5] Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts [J].

Chandra, Manish ;

Xu, Qiang .

JOURNAL OF POWER SOURCES, 2007, 168 (01) :135-142

[6] A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia-borane [J].

Chandra, Manish ;

Xu, Qiang .

JOURNAL OF POWER SOURCES, 2006, 156 (02) :190-194

[7] In situ XAFS and NMR study of rhodium-catalyzed dehydrogenation of dimethylamine borane [J].

Chen, YS ;

Fulton, JL ;

Linehan, JC ;

Autrey, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3254-3255

[8] Ni1-xPtx (x=0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia borane [J].

Cheng, Fangyi ;

Ma, Hua ;

Li, Yueming ;

Chen, Jun .

INORGANIC CHEMISTRY, 2007, 46 (03) :788-794

[9] Highly efficient colloidal cobalt- and rhodium-catalyzed hydrolysis of H3N•BH3 in air [J].

Clark, Timothy J. ;

Whittell, George R. ;

Manners, Ian .

INORGANIC CHEMISTRY, 2007, 46 (18) :7522-7527

[10] Homogeneous, titanocene-catalyzed dehydrocoupling of amine-borane adducts [J].

Clark, Timothy J. ;

Russell, Christopher A. ;

Manners, Ian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9582-9583

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