Molecular Interactions in Binary Liquid Mixtures of Cyclohexanone with Morpholine, Bromobenzene and Anisole at 308.15 K and 318.15 K

被引:9
|
作者
Venis, A. Rose [1 ]
Rajkumar, X. Rosario [2 ]
机构
[1] St Josephs Coll Autonomous, Dept Chem, Tiruchirappalli 620002, Tamil Nadu, India
[2] Oxford Engn Coll, Tiruchirappalli 620009, Tamil Nadu, India
关键词
Density; Viscosity; Ultrasonic velocity; Adiabatic compressibility; Acoustic impedance; EXCESS THERMODYNAMIC PROPERTIES; MOLAR VOLUMES; VISCOSITIES; ALKANOLS; POLAR; PARAMETERS; DENSITIES; DODECANE; SOLVENTS; DECANE;
D O I
10.14233/ajchem.2014.16182
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities, viscosities and ultrasonic velocities have been measured for the binary mixtures of cyclohexanone with morpholine, bromobenzene and anisole at 308.15 K and 318.15 K over the entire range of mole fraction. Thermodynamic parameters like excess volume, adiabatic compressibility, free volume, linear free energy, acoustic impedance and viscosity are calculated. From these values the excess properties are also calculated. The deviations of the liquid mixture from ideality have been explained based on the nature molecular interactions between unlike molecules.
引用
收藏
页码:4711 / 4715
页数:5
相关论文
共 50 条