Processing of Polymer Nanocomposites Reinforced with Polysaccharide Nanocrystals

被引:187
作者
Dufresne, Alain [1 ]
机构
[1] Int Sch Paper Print Media & Biomat Pagora, Grenoble Inst Technol, F-38402 St Martin Dheres, France
来源
MOLECULES | 2010年 / 15卷 / 06期
关键词
cellulose; nanocomposites; processing; nanocrystals; whiskers; microfibrils; NATURAL-RUBBER NANOCOMPOSITES; SORBITOL PLASTICIZED STARCH; STRAW CELLULOSE WHISKERS; MECHANICAL-PROPERTIES; MICROCRYSTALLINE CELLULOSE; BACTERIAL CELLULOSE; POLYVINYL-ALCOHOL; MICROFIBRILLATED CELLULOSE; FIBRILLATED CELLULOSE; CHEMICAL-MODIFICATION;
D O I
10.3390/molecules15064111
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Aqueous suspensions of polysaccharide (cellulose, chitin or starch) nanocrystals can be prepared by acid hydrolysis of biomass. The main problem with their practical use is related to the homogeneous dispersion of these nanoparticles within a polymeric matrix. Water is the preferred processing medium. A new and interesting way for the processing of polysaccharide nanocrystals-based nanocomposites is their transformation into a co-continuous material through long chain surface chemical modification. It involves the surface chemical modification of the nanoparticles based on the use of grafting agents bearing a reactive end group and a long compatibilizing tail.
引用
收藏
页码:4111 / 4128
页数:18
相关论文
共 117 条
  • [1] Thermoplastic starch-waxy maize starch nanocrystals nanocomposites
    Angellier, H
    Molina-Boisseau, S
    Dole, P
    Dufresne, A
    [J]. BIOMACROMOLECULES, 2006, 7 (02) : 531 - 539
  • [2] Processing and structural properties of waxy maize starch nanocrystals reinforced natural rubber
    Angellier, H
    Molina-Boisseau, S
    Lebrun, L
    Dufresne, A
    [J]. MACROMOLECULES, 2005, 38 (09) : 3783 - 3792
  • [3] Mechanical properties of waxy maize starch nanocrystal reinforced natural rubber
    Angellier, H
    Molina-Boisseau, S
    Dufresne, A
    [J]. MACROMOLECULES, 2005, 38 (22) : 9161 - 9170
  • [4] Starch nanocrystal fillers in an acrylic polymer matrix
    Angellier, H
    Putaux, JL
    Molina-Boisseau, S
    Dupeyre, D
    Dufresne, A
    [J]. MACROMOLECULAR SYMPOSIA, 2005, 221 : 95 - 104
  • [5] Surface chemical modification of waxy maize starch nanocrystals
    Angellier, H
    Molina-Boisseau, S
    Belgacem, MN
    Dufresne, A
    [J]. LANGMUIR, 2005, 21 (06) : 2425 - 2433
  • [6] Plasticized starch/tunicin whiskers nanocomposites.: 1.: Structural analysis
    Anglès, MN
    Dufresne, A
    [J]. MACROMOLECULES, 2000, 33 (22) : 8344 - 8353
  • [7] Plasticized starch/tunicin whiskers nanocomposite materials.: 2.: Mechanical behavior
    Anglès, MN
    Dufresne, A
    [J]. MACROMOLECULES, 2001, 34 (09) : 2921 - 2931
  • [8] [Anonymous], POLYMER
  • [9] Flow properties of microcrystalline cellulose suspension prepared by acid treatment of native cellulose
    Araki, J
    Wada, M
    Kuga, S
    Okano, T
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 142 (01) : 75 - 82
  • [10] Steric stabilization of a cellulose microcrystal suspension by poly(ethylene glycol) grafting
    Araki, J
    Wada, M
    Kuga, S
    [J]. LANGMUIR, 2001, 17 (01) : 21 - 27