Optimization of gas diffusion layer in high temperature PEMFC with the focuses on thickness and porosity

被引:112
作者
Xia, Lingchao
Ni, Meng [1 ]
He, Qijiao
Xu, Qidong
Cheng, Chun
机构
[1] Hong Kong Polytech Univ, Dept Bldg & Real Estate, Res Inst Sustainable Urban Dev RISUD, Hung Hom,Kowloon, Hong Kong, Peoples R China
关键词
HT-PEMFC; Gas diffusion layer; Geometric optimization; Porosity; Flow uniformity; MEMBRANE FUEL-CELLS; 2-PHASE FLOW; PERFORMANCE; CO; DYNAMICS; CATALYST; CHANNEL;
D O I
10.1016/j.apenergy.2021.117357
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Wide ranges of thickness (e.g. 100-400 mu m) and porosity (e.g. 30-70%) of gas diffusion layer (GDL) in a high temperature proton exchange membrane fuel cell (HT-PEMFC) are available in the literature. However, the effects of GDL porosity and thickness on electron conduction and gas distribution uniformity (under the rib and under the channel) are unclear. In this study, a numerical non-isothermal 3D model was developed. After model validation, parametric analyses were performed to investigate the effects of thickness and porosity on flow uniformity (under the rib and under the channel), diffusion flux and ohmic resistance. It is found that both the flow uniformity and ohmic resistance increase with increasing thickness and porosity. However, the thickness and porosity have opposite influence on diffusion flux, which decreases with increasing GDL thickness but increases with increasing porosity. Unlike the previous research suggesting thin GDL with high porosity, optimal GDL thickness and porosity are found in the present study. The appropriate GDL thicknesses for anode and cathode are 80-120 mu m and 140-170 mu m respectively while the optimal value for GDL porosity is 35-45%. This study clearly demonstrates that we can further achieve a performance increment of 7.7% by carefully controlling the thickness and porosity of GDL.
引用
收藏
页数:12
相关论文
共 38 条
[1]   High temperature PEM fuel cell performance characterisation with CO and CO2 using electrochemical impedance spectroscopy [J].
Andreasen, Soren Juhl ;
Vang, Jakob Rabjerg ;
Kaer, Soren Knudsen .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (16) :9815-9830
[2]   Proton-conducting membranes based on benzimidazole polymers for high-temperature PEM fuel cells. A chemical quest [J].
Antonio Asensio, Juan ;
Sanchez, Eduardo M. ;
Gomez-Romero, Pedro .
CHEMICAL SOCIETY REVIEWS, 2010, 39 (08) :3210-3239
[3]  
Benner J., 2018, ASME INT MECH ENG C
[4]   Modelling of CO Poisoning and its Dynamics in HTPEM Fuel Cells [J].
Bergmann, A. ;
Gerteisen, D. ;
Kurz, T. .
FUEL CELLS, 2010, 10 (02) :278-287
[5]   The influence of CO on the current density distribution of high temperature polymer electrolyte membrane fuel cells [J].
Boaventura, M. ;
Sander, H. ;
Friedrich, K. A. ;
Mendes, A. .
ELECTROCHIMICA ACTA, 2011, 56 (25) :9467-9475
[6]   CO tolerance and durability study of PtMe (Me = Ir or Pd) electrocatalysts for H2-PEMFC application [J].
Brouzgou, Angeliki ;
Seretis, Antonis ;
Song, Shuqin ;
Shen, Pei Kang ;
Tsiakaras, Panagiotis .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (26) :13865-13877
[7]  
Chase MW., 1998, J PHYS CHEM REF DATA, V9, P1, DOI 10.18434/T42S31
[8]   Recent progress of gas diffusion layer in proton exchange membrane fuel cell: Two-phase flow and material properties [J].
Chen, Qin ;
Niu, Zhiqiang ;
Li, Hongkun ;
Jiao, Kui ;
Wang, Yun .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (12) :8640-8671
[9]   Numerical modeling and experimental study of the influence of GDL properties on performance in a PEMFC [J].
Chun, Jeong Hwan ;
Park, Ki Tae ;
Jo, Dong Hyun ;
Kim, Sang Gon ;
Kim, Sung Hyun .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (02) :1837-1845
[10]  
Coker A.K., 2007, LUDWIGS APPL PROCESS, V1, P827