The Anderson-type anion (TeMo6O24)6- -: A multidentate ligand for trivalent rare earth cations

被引：58
作者：
Drewes, D [1 ]
Limanski, EM [1 ]
Krebs, B [1 ]
机构：
[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 24期
关键词：
polyoxometalates; molybdenum; lanthanides; tellurium; self-assembly;
D O I：
10.1002/ejic.200400525
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The syntheses and structural characterizations of four novel lanthanide polyoxomolybdates containing the Anderson-type anion (TeMO6O24)(6-) are presented. Depending on the size of the trivalent rare earth cations, in the solid-state structures of {[La(H2O)(6)](2)(TeMo6O24)}(n).6nH(2)O (1), {[Ce(H2O)(7)](2)-(TeMo6O24)}(n).7nH(2)O (2), {[Pr(H2O)(7)](2)(TeMo6O24)}(n).8nH(2)O (3) and {[Nd(H2O)(7)](2)(TeMo6O24)}(n).8nH(2)O (4) two different arrangements of the building unit are present. The (TeMo6O24)(6-) anion acts as a hexadentate ligand for La-III and as a tetradentate ligand for Ce-III, Pr-III and Nd-III, leading to two different infinite one-dimensional chains. The crystal structures of the new compounds are compared with known lanthanide polyoxomolybdates containing the (TeMo6O24)(6-) anion and the influence of the Ln(III) ionic radii is discussed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码：4849 / 4853
页数：5
相关论文
共 25 条
  • [1] [Anonymous], 2015, Acta Crystallogr., V71, P3
  • [2] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
    BROWN, ID
    ALTERMATT, D
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
  • [3] Formation of large clusters in the reaction of lanthanide cations with heptamolybdate
    Burgemeister, K
    Drewes, D
    Limanski, EM
    Küper, I
    Krebs, B
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (13) : 2690 - 2694
  • [4] A series of novel lanthanide polyoxometalates: condensation of building blocks dependent on the nature of rare earth cations
    Drewes, D
    Limanski, EM
    Krebs, B
    [J]. DALTON TRANSACTIONS, 2004, (14) : 2087 - 2091
  • [5] A SMART CATALYST THAT SELF-ASSEMBLES UNDER TURNOVER CONDITIONS
    HILL, CL
    ZHANG, X
    [J]. NATURE, 1995, 373 (6512) : 324 - 326
  • [6] INOUYE Y, 1991, CHEM PHARM BULL, V39, P1638
  • [7] Solid-state and solution studies of {Lnn(SiW11O39)} polyoxoanions:: An example of building block condensation dependent on the nature of the rare earth
    Mialane, P
    Lisnard, L
    Mallard, A
    Marrot, J
    Antic-Fidancev, E
    Aschehoug, P
    Vivien, D
    Sécheresse, F
    [J]. INORGANIC CHEMISTRY, 2003, 42 (06) : 2102 - 2108
  • [8] Müller A, 1999, ANGEW CHEM INT EDIT, V38, P3241, DOI 10.1002/(SICI)1521-3773(19991102)38:21<3241::AID-ANIE3241>3.0.CO
  • [9] 2-9
  • [10] Molecular growth from a Mo176 to a Mo248 cluster
    Müller, A
    Shah, SQN
    Bögge, H
    Schmidtmann, M
    [J]. NATURE, 1999, 397 (6714) : 48 - 50
123