Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst

被引：128
|
作者：
Bruneau-Voisine, Antoine [1 ]
Wang, Ding [1 ]
Dorcet, Vincent [2 ]
Roisnel, Thierry [2 ]
Darcel, Christophe [1 ]
Sortais, Jean-Baptiste [1 ,2 ,3 ,4 ]
机构：
[1] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes,Team Organometall Mat & Cata, 263 Ave Gen Leclerc, F-35042 Rennes, France
[2] Univ Rennes 1, CNRS, UMR 6226, Inst Sci Chim Rennes,Ctr Diffractometrie 10, 263 Ave Gen Leclerc, F-35042 Rennes, France
[3] Inst Univ France, 1 Rue Descartes, F-75231 Paris 5, France
[4] Univ Toulouse, CNRS, LCC, INPT,UPS, 205 Route Narbonne, F-31077 Toulouse 4, France
来源：
ORGANIC LETTERS | 2017年 / 19卷 / 13期
关键词：
WELL-DEFINED MANGANESE; BULKY BIPYRIDINE LIGANDS; PNP PINCER COMPLEXES; CO2; REDUCTION; KETONE HYDROSILYLATION; 2-(AMINOMETHYL) PYRIDINE; ORGANIC-SYNTHESIS; COBALT CATALYSIS; OSMIUM COMPLEXES; PRIMARY ALCOHOLS;
D O I：
10.1021/acs.orglett.7b01657
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A very simple and inexpensive catalytic system based on abundant manganese as transition metal and on an inexpensive phosphine-free bidendate ligand, 2-(aminomethyl)pyridine, has been developed for the reduction of a large variety of carbonyl derivatives with 2-propanol as hydrogen donor. Remarkably, the reaction proceeds at room temperature with low catalyst loading (down to 0.1 mol %) and exhibits a good tolerance toward functional groups. High TON (2000) and TOF (3600 h(-1)) were obtained.
引用
收藏
页码：3656 / 3659
页数：4
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